If bunches of protons are being circulated in both directions of the LHC collider with each proton having an energy $E_p=7\ \mathrm{TeV}$, then using the following "Lorentz Invariant Quantity" expression, $s$, for a collider:
$$s=4E_p^2$$
I can then take the square root $s$ to get
$$\sqrt{s}=\sqrt{4\times7^2}\ \mathrm{TeV}=14\ \mathrm{TeV}$$
Which is the center of mass energy for proton-proton collisions at the LHC.
I found the expression, $s$ on the top of page 5 of some Oxford university notes. However, I don't really get where $s$ was derived from, so I am not sure why it has a different form for this type of proton-proton collision.