$\newcommand{\vect}[1]{{\bf #1}}$
Imagine you have a body $\Omega$ and you want to understand how it responds to some external load.
Do do this, imagine you cut the body with a plane, say the plane whose normal vector is the $\hat{x}$ vector. Now select an element of area $\delta A$ and measure how the force on the element, I will call it ${\rm d}\vect{F}$.
Define the numbers
$$
\tau_{xx} = \lim_{\Delta A \to 0}\frac{\Delta F_x}{\Delta A}, ~~~
\tau_{yx} = \lim_{\Delta A \to 0}\frac{\Delta F_y}{\Delta A}, ~~~
\tau_{zx} = \lim_{\Delta A \to 0}\frac{\Delta F_z}{\Delta A}
$$
You can see that
It is important to label this element with out choice of the orientation for the cutting plane. In this case we select $\hat{x}$, but in general it could be any normal vector $\vect{n}$
The definition of $\tau$ resembles that of pressure. Indeed, if you consider the element $\tau_{xx}$ you'd get the force per unit area perpendicular to the are element along the $x$ direction.
The stress tensor is just the collection
$$
\tau = \left(\begin{array}{ccc}
\tau_{xx} & \tau_{yx} & \tau_{zx} \\
\tau_{xy} & \tau_{yy} & \tau_{zy} \\
\tau_{xz} & \tau_{yz} & \tau_{zz} \\
\end{array}\right)
$$
The average pressure could then be defined as
$$
\pi = \frac{1}{3}(\tau_{xx} + \tau_{yy} + \tau_{zz})
$$