I assume your question was asked with the implicit "and everything else is kept the same" (still GR + standard model, just with one parameter tweaked).
This would have a large effect, because now the neutron would be much more stable! The neutron is already quite stable (~ 10 minute half life), due to the tight energy constraints in the reaction decaying to a proton, electron, and electron antineutrino.
mass of neutron (939.565378 MeV/c^2) - mass of proton (938.272046 MeV/c^2) = 1.293332 MeV/c^2
This is roughly the mass of an electron (in our actual universe), 511 keV/c^2. After doubling the electron mass, instead of ~ 782 keV of available energy to share kinematically amongst the products, it drops to about third of this. (Related question: Why is the free neutron lifetime so long?)
This would greatly affect the primordial nucleosynthesis after the big bang. The initial neutron-to-proton ratio would be changed drastically. The main reactions leading to their 1-to-7 initial equilibrium involve a process similar to neutron decay or its reverse. Likely neutrons and protons would now occur much closer to equal initial densities with the heavier electron mass. This means after freeze out there would be much more helium than hydrogen. Much of the fuel of stars would already be consumed! (NOTE: I am unsure of the actual effect on primordial nucleosynthesis and if someone could comment further on this, instead of my handwavy guess, it would be appreciated.)
Furthermore, the change in electron mass will also affect the kinematics of the main star fusion processes.
The first step of the main fusion process currently in our sun, is the fusing of protons to yield helium II which then decays to deuterium and an positron. These steps are the rate limiting steps for our sun, and essentially control its lifetime. The decay to deuterium is so kinematically constrained that the excess energy is less than the mass of an electron:
$$ {}^1_1 H + {}^1_1 H \rightarrow {}^2_1 D + e^+ + \nu_e + 0.42 \ \mathrm{MeV} $$
The dominant decay route of helium II is to just decay by proton emission back to two protons. Therefore the main fusion process of our sun will fail to 'ignite', if the mass of the electron was double its current value.
Several steps in the CNO hydrogen burning cycle are also quite energy constrained. The most constrained of which is the following involving Nitrogen-13
$${}^{13}_7 N \rightarrow {}^{13}_6 C + e^+ + \nu_e + 1.20 \ \mathrm{MeV}$$
So doubling the electron mass will roughly halve the available energy for that step.
The cosmos as we know it would be wildly different if the electron mass was doubled, due mainly I believe to the kinematic restrictions in reactions involving nucleons.
Some other changes:
Chemical bond energies are roughly proportional to the mass of the electron. The characteristic radius goes as the inverse of the electron mass. Bond angles and predominant oxidation states of the elements will stay the same. So comparatively, chemistry will not change as much. The phase state diagrams will likely look similar, just scaled in energy.