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The pressure of a gas of particles is $P = \frac{N}{V}mv_x^2$, where $v_x$ is the root mean square velocity of the particles in the $x$-direction, $m$ is the mass of each particle, $N$ is the total number of particles in a volume $V$. How does one derive this from basic principles? I understand that $\frac{N}{V}m$ is the density of the gas. But why does multiplying it with the square of the RMS velocity give the pressure?

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Well, We know that $$E=\frac{3}{2}k_BT=\frac{1}{2}m\langle v^2\rangle $$ $$PV=Nk_BT\Rightarrow PV=\frac{N}{3}m\langle v^2\rangle $$ $$\rightarrow P=\frac{N}{3V}m\langle v^2\rangle$$ Considering space is isotropic, $$\langle v_x^2\rangle =\langle v_y^2\rangle =\langle v_z^2\rangle =\frac{1}{3}\langle v^2\rangle $$ $$\rightarrow \boxed{P=\frac{N}{V}m\langle v_x^2\rangle }$$

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  • $\begingroup$ Thanks. How did you get $E = \frac{3}{2}k_B T$. Sorry, my knowledge of statistical mechanics is a little lacking. Is it just a standard definition for a gas of (mono-atomic) particles? $\endgroup$
    – Matrix23
    Commented Jul 4, 2021 at 8:56
  • $\begingroup$ This follows from the Equipartition theorem. $\endgroup$
    – Himanshu
    Commented Jul 4, 2021 at 10:07

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