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This is the question I'm struggling with:

Given

$\left<p|q\right> = \frac{e^{-ipq/h}}{\sqrt{2\pi h}}$

and that

$\hat{H} = \frac{\hat{P^2}}{2m} + V(\hat{Q})$

show that:

$\left<p|\hat{H}(\hat{P}, \hat{Q})|q\right> = \frac{e^{-ipq/h}}{\sqrt{2\pi h}} \cdot H(p,q)$

My working is as follows:

$\left<p|\hat{H}(\hat{P}, \hat{Q})|p\right> = H(p,q)$

$\left<p|\hat{H}(\hat{P}, \hat{Q})|q\right> = \left<p|\hat{H}(\hat{P}, \hat{Q})|p\right> \left<p|q\right>$

$= \frac{e^{-ipq/h}}{\sqrt{2\pi h}} \cdot H(p,q)$

but this is wrong. Any help would be very much appreciated.

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    $\begingroup$ Try working out the terms $\langle p|\hat p^2/(2m)|q\rangle $ and $\langle p| V(\hat Q)|q\rangle $ one by one. The Ansatz $\langle p| \hat H (\hat P, \hat Q)|p\rangle$ does not help and is not equal to $\langle p| \hat H (\hat P, \hat Q)|q\rangle$. $\endgroup$
    – Hans Wurst
    Commented May 6, 2021 at 15:10

1 Answer 1

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\begin{align*} \langle p|H|q\rangle &= \left\langle p\left|\frac{P^2}{2m}+V(Q)\right|q\right\rangle \\ &= \left\langle p\left|\frac{P^2}{2m}\right|q\right\rangle + \langle p|V(Q)|q\rangle \\ &= \frac{1}{2m}\langle p|P^2|q\rangle +\langle p|V(Q)|q\rangle \\ &= \frac{p^2}{2m}\langle p|q\rangle +V(q)\langle p|q\rangle \\ &= H(q,p)\cdot \langle p|q\rangle \end{align*} where we have used : $$P|p\rangle=p|p\rangle$$ $$Q|q\rangle =q|q\rangle $$

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