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A heat reservoir (Figure above) is a constant temperature heat source or sink. Because the temperature is uniform, there is no heat transfer across a finite temperature difference and the heat exchange is reversible. From the definition of entropy ( $ dS = dQ_\textrm{rev}/T$ ), $\displaystyle \Delta S = \frac{Q}{T},$

How is the heat exchange reversible if a reservoir is at constant temperature? Can anyone please help me. I'm getting confused. Thank you.

Article link here https://web.mit.edu/16.unified/www/FALL/thermodynamics/notes/node41.html

Similarly done by "Blundell and Blundell" pg 142 ,2 ed,They take the heat flow between the system and large reservoir to be reversible.

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  • $\begingroup$ What is it that you don’t understand? The answer is basically written above. $\endgroup$
    – joseph h
    Commented Jan 30, 2021 at 8:30
  • $\begingroup$ If a large reservoir has constant temperature how does that mean that the process is reversible? $\endgroup$
    – Kashmiri
    Commented Jan 30, 2021 at 8:31
  • $\begingroup$ Heat transfer is irreversible when it occurs over a temperature gradient. There are no temperature gradients in an ideal thermal reservoir. $\endgroup$
    – Bob D
    Commented Jan 30, 2021 at 11:41
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    $\begingroup$ Yes but there does exist a gradient between reservoir and the system. Won't that finite difference cause the process to be irreversible? $\endgroup$
    – Kashmiri
    Commented Jan 30, 2021 at 17:28

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How is the heat exchange reversible if a reservoir is at constant temperature? Can anyone please help me. I'm getting confused. Thank you.

Heat transfer is irreversible when it occurs over a temperature gradient. There are no temperature gradients within an ideal thermal reservoir. So heat transfer to or from an ideal thermal reservoir is reversible. However, this only applies to the reservoir, and not necessarily the system that is exchanging heat with the reservoir.

For the heat transfer to be considered reversible with respect to the system, the temperature difference between the system and reservoir must be infinitesimal. If a temperature gradient exists at the boundary, heat transfer across that gradient is an irreversible process that generates entropy. Since no gradients exist in an ideal thermal reservoir the temperature gradient is considered to exist within the system. Therefore, all the entropy generated for an irreversible process is assumed to occur within the system, and none in the reservoir.

Hope this helps.

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  • $\begingroup$ Thank you dear Bob D. If there exists a finite temperature difference between the system and the reservoir then the change is going to be irreversible. As you helped me out here physics.stackexchange.com/questions/611066/… $\endgroup$
    – Kashmiri
    Commented Jan 30, 2021 at 17:29

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