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My question is why can we exchange the variation and gradient in the following equation that I found in some paper: $$\int \phi \, \delta(-\vec{\nabla}\cdot \vec{P})\, dV = \int \nabla\phi (\delta \vec{P})\, dV.$$

Is there some derivative rule that I am not familiar with or is it the peculiarity of the situation?

Here is some background: A variation on the form of electrostatic energy of a polarization density field $\vec{P}$ can be written like this

$$\delta E=\int \phi \,\delta\rho\, dV.$$

Here, $\phi$ is the electric potential and $\rho$ is bound charge density. From Gauss' law we can write the dipole charge density with the polarization field,

$$\rho=-\vec{\nabla}\cdot \vec{P}.$$

Inserting this into the first equation we get

$$\int \phi \, \delta(-\vec{\nabla}\cdot \vec{P})\, dV = \int \nabla\phi (\delta \vec{P})\, dV.$$

Edit 1:

There seems to be a divergence theorem at work here. First we see that $$\delta(\vec{\nabla}\cdot \vec{P})=\vec{\nabla} \cdot \delta \vec{P}.$$

Our original integral can now be rewritten, so that

$$\int \phi \, \delta(-\vec{\nabla}\cdot \vec{P})\, dV = -\int \phi \, \delta(\vec{\nabla}\cdot \vec{P})\, dV = -\int \phi \,(\vec{\nabla} \cdot \delta \vec{P})\, dV.$$

The product rule for multiplication by scalar gives us

$$\vec{\nabla}\cdot(\phi \,\delta \vec{P} )=(\nabla \phi)\cdot \delta\vec{P}+\phi( \vec{\nabla}\cdot \delta \vec{P}),$$

so the last integral can again be rewritten so that

$$-\int \phi \,(\vec{\nabla} \cdot \delta \vec{P})\, dV=-\left(\int[\vec{\nabla}\cdot(\phi \,\delta \vec{P} )-(\nabla \phi)\cdot \delta\vec{P}]\, dV \right).$$

The divergence theorem can be applied to the first integral on the right hand side of the last equation, so that

$$\int\vec{\nabla}\cdot(\phi \,\delta \vec{P} )\, dV=\oint_S(\phi \,\delta \vec{P} )\cdot \vec{n}\, dS.$$

If the last integral is equal to zero, which seems to be the case here, than the final expression is

$$\int \phi \, \delta(-\vec{\nabla}\cdot \vec{P})\, dV=\int \nabla\phi (\delta \vec{P})\, dV.$$

The only thing to figure out now is why the surface integral should be equal to zero.

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  • $\begingroup$ I don't think there is a derivative rule that works like that. It seems that a surfafe term vanishes, but the signs do not match. Can you also add the paper??? $\endgroup$
    – Noone
    Commented Apr 22, 2020 at 13:39
  • $\begingroup$ Vector field of scalars, like electric potential, is assumed to be zero. Thus, zero gradient of electric potential makes last integral zero. $\endgroup$ Commented May 21, 2020 at 8:38
  • $\begingroup$ Would Mathematics be a better home for this question? $\endgroup$
    – Qmechanic
    Commented May 21, 2020 at 9:17

1 Answer 1

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The answer lies in the divergence theorem. In the expression

$$\int \phi \,(\vec{\nabla} \cdot \delta \vec{P})\, dV=\int[\vec{\nabla}\cdot(\phi \,\delta \vec{P} )-(\nabla \phi)\cdot \delta\vec{P}]\, dV, $$

the first integral on the right hand side is equal to zero by virtue of the divergence theorem; since the potential far away from the plates is constant and equal to zero.

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