The covariant derivative for a fermion with a symmetry group $SU(N)$ is given by $$ D_\nu \psi = \partial_\nu \psi -i g A^A_\nu t_A \, \psi, \tag{1} $$ where $A^A_\nu$ is a gauge field, $g$ is a coupling constant, $t_A$ is a generator of the Lie algebra $\mathfrak{su}(n)$, and the indices $A,B,\cdots=1,2,\cdots,N^2-1$.
For fermions in the fundamental representation, eq. (1) can be written as $$ D_\nu \psi^a = \partial_\nu \psi^a -i g A^A_\nu (t_A)^a{}_b \, \psi^b, \tag{2} $$ where the indices $a,b=1,2,\cdots,N$. So if $N=2$, the fermion $\psi$ can represented by $$\psi =\left( \begin{matrix} \psi_1 \\ \psi_2 %\\\psi_3 \end{matrix} \right) $$
But for fermions in the adjoint representation, the generators $(t_A){}^B{}_C = i f_A{}^B{}_C$, which are $3\times 3$ matrices in the case of $SU(2)$. The covariant derivative can be written as
$$
D_\nu \psi^A = \partial_\nu \psi^A -i g A^A_\nu (t_A)^A{}_B, \psi^B.\tag{3}
$$
Therefore the fermion field must be represented by
$$\psi=\left(
\begin{matrix}
\psi_1 \\ \psi_2 \\\psi_3
\end{matrix}
\right).
$$
But I am not sure that what I have expressed above is correct.