It's generally stated in the textbooks that when the Higgs field acquires a certain VEV the corresponding symmetry is spontaneously broken. For example in QFT in a Nutshell by A. Zee:
But none of the $SU(2)$ transformations leaves $\binom{0}{v}$ invariant: The vacuum expectation value of φ spontaneously breaks the entire $SU(2)$ symmetry
I was wondering why this should be the case. We have a Lagrangian of the form
$$ \bar \Psi_L \Phi \psi_R ,$$
where $\Psi_L$ is the lepton doublet and $\Phi$ the Higgs doublet. This term is obviously invariant under $\Psi_L \rightarrow U \Psi_L$ and $\Phi \rightarrow U \Phi $:
$$ \bar \Psi_L \Phi \psi_R \rightarrow \bar \Psi_L U^\dagger U \Phi \psi_R = \bar \Psi_L \Phi \psi_R$$
Regarding Zee's explanation: A general $\Phi= \binom{\Phi_1}{\Phi_2}$ isn't invariant under $SU(2)$ transformations either, but this is not what is important here. Only the complete term in the Lagrangian must be invariant and it is regardless of if we put in some vev or a general $\Phi$.
Now, if we put in a certain $\Phi= \binom{0}{v}$, we still have
$$ \bar \Psi_L \Phi \psi_R= \bar \Psi_L \binom{0}{v} \psi_R \rightarrow \bar \Psi_L U^\dagger U \binom{0}{v} \psi_R = \bar \Psi_L \binom{0}{v} \psi_R .$$
The same holds true if we write this term a little different, as it is usually done, using $\Psi_L = \binom{\nu}{e}$:
$$ \bar \Psi_L \Phi \psi_R = \binom{\bar \nu}{\bar e}^T \binom{0}{v} \psi_R = 0 \cdot \bar \nu \psi_R + v \cdot \bar e \psi_R $$
The symmetry is still there only "hidden" a little bit.
What exactly breaks here the symmetry and how can it be shown explicitly?