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An important extensive property of all systems in thermodynamics, statistical mechanics, and information theory, quantifying their disorder (randomness), i.e., our lack of information about them. It characterizes the degree to which the energy of the system is *not* available to do useful work.

1 vote
2 answers
159 views

is entropy the same up to a constant?

I have understood that what's important about entropy is its change $\Delta S$, not $S$ itself, much like the electrostatic potential. … Therefore, can I assume that a constant entropy can be redefined to be zero? In particular, I have, for high temperatures, $S=2+\Sigma n_{i}ln(n_{i})$, Can I say that $S=\Sigma n_{i}ln(n_{i})$ ? …
Juan Pablo Arcila's user avatar
0 votes
1 answer
56 views

three particles on a state with negative energy have negative temperature?

Suppose three particles on a state with energy $-\epsilon$, that is, $H\lvert\Phi_1\rangle=-\epsilon\lvert\Phi_1\rangle$, as the average energy per particle is $kT$, but is also $-\epsilon/3$, wouldn' …
Juan Pablo Arcila's user avatar
7 votes
2 answers
1k views

Heat transfer reservoir and system at same temperature

I just read that "a heat transfer between a reservoir and a system at same temperature is a reversible process". If there's no temperature difference, why would there be a heat flow?
Juan Pablo Arcila's user avatar
1 vote
3 answers
1k views

Infinite entropy in ideal gas

Does it make sense that entropy goes to infinity as temperature goes to infinity? … I was used to finding asymptotic behaviours for entropy as a function of temperature, so this result is confusing me …
Juan Pablo Arcila's user avatar