I think the simplest way to understand why we cannot have a joint probability distribution for two incompatible observables $A,B$ (meaning non-commuting) is the following. With a slight abuse of of notation, the joint probability is defined as: $$ P_{A,B}(a,b) := \mathrm{Prob}(A=a,B=b) $$ which means, it's the probability of $A$ having value $a$ and $B$ having value $b$. In quantum mechanics this means that there is an eigenstate of $A$ with eigenvalue $a$ and an eigenstate of $B$ with eigenvalue $b$. But if $[A,B]\neq 0$ this is notoriously not possible. Note that, conversely, if $A$ and $B$ commute it is always possible to find a common eigenbasis and so the above prescription works fine. This argument, however does not answer the other part of the question. Which is: > Why can I not define a *bona fide* characteristic function (i.e. which is the Fourier transform of a probability density) in case of non-compatible observables? And perhaps, is there any way to amend this? As pointed correctly by the OP this has to do with Bochner's theorem which tells precisely what requirements a characteristic function has to satisfy. I will state Bochner's theorem in the form needed for our purposes. > **Theorem (Bochner)** $\chi (t)$ is the Fourier transform of a probability density $P(\omega)$ if and only if for any $n$-tuple $t_1,t_2,\ldots t_n$ the matrix with entries $\chi_{i,j}:= \chi(t_i-t_j)$ is non-negative definite (and hermitian). A simple way to understand Bochner's theorem is the following. A matrix $\chi$ is non-negative definite if and only if it can be written as $\chi = A A^\dagger$. Let $P(\omega)$ be the Fourier transform of $\chi$, that is $$ \chi_{i,j} := \int d\omega e^{i(t_i-t_j) \omega} P(\omega) $$ which we write as \begin{align} \chi_{i,j} &:= \int d\omega e^{it_i \omega} P(\omega) e^{-it_j \omega} \\ & = (A A^\dagger)_{i,j} \end{align} with $$ A_{i,\omega} := e^{it_i \omega} \sqrt{P(\omega)} $$ which we can do since $P(\omega)$ is non-negative. So $P(\omega)$ non-negative means that $\chi_{i,j}$ is a non-negative definite matrix. This characterizes characteristic functions in the classical case. Let us now turn to the quantum mechanics and consider the multivariate case, i.e., we have several observables which I call $X_1, X_2, \ldots X_n$ with spectra in $\omega_1, \ldots, \omega_n$. The conjugate variables being $t_1,\ldots,t_n$, and the notation $$tX:=\sum_{k=1}^n t_k X_k$$ In this case the characteristic function is $$ \chi(t):=\mathsf{E}[ e^{itX} ]= \operatorname{Tr} ( e^{itX} \rho ) $$ for some quantum state $\rho$ (a normalized non-negative matrix). We want to check under which conditions $\chi_{i,j}=\chi(t_1-t_j)$ is non-negative definite as a matrix. If the $X_k$ were mutually commuting operators we would have $$ e^{i(t_i-t_j) X} = e^{it_i X} e^{-it_j X} \ \ \ \ \ \ (1) $$ and then we could write \begin{align} \chi_{i,j} &=\operatorname{Tr} \left ( e^{i(t_i-t_j) X} \rho \right) \\ &=\operatorname{Tr} \left ( e^{it_i X} e^{-it_j X} \rho \right ) \\ &=\operatorname{Tr} \left (e^{-it_j X} \sqrt{\rho} \sqrt{\rho} e^{it_i X} \right ) \end{align} Now define the matrix $A_{j,lq} := \left ( e^{-it_j X} \sqrt{\rho} \right )_{l,q} =: A_{i,\xi}$ where $\xi=(l,q)$. We have $$ \chi_{i,j} = \sum_{lq} A_{j,lq} \overline{A_{j,lq}} $$ which is of the form $BB^\dagger$ and proves that $\chi_{i,j}$ is non-negative definite. Obviously this whole construction breaks down if $X_k$ are not mutually commuting. Since the condition in Bochner's theorem is an if and only if, in this case $\chi(t)$ is not the Fourier transform of a probability distribution