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# Questions tagged [time-evolution]

The quantum mechanical time evolution operator governs how observables and/or states evolve during finite time steps, and is always unitary. Use this tag for questions about the time evolution operator, or the different equations of motion in the Schrödinger/Heisenberg/Dirac pictures. For time-independent Hamiltonians, the time evolution operator is simply exp(-iHt).

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### Phase in time evolution operator for time-dependent Hamiltonian [duplicate]

In Quantum Mechanics, a state vector $|\psi\rangle$ will evolve in time according to $$|\psi(t)\rangle=e^{-\frac{i}{\hbar}\hat H t}|\psi(0)\rangle$$ Imagine we have a system such that, for a short ...
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### Solving the Schrodinger equation with a time-dependent Hamiltonian

I am trying to find the general solution to the Schrodinger equation with a time-dependent Hamiltonian: $$i \frac{\partial}{\partial t}| \psi(t) \rangle = H(t) | \psi(t) \rangle.$$ My Hamiltonian ...
870 views

### How do base kets satisfy Schrödinger's equation in Schrödinger picture and why don't they evolve with time?

According to Sakurai, eigenvalue equation for an operator $A$, $A|a'\rangle=a'|a'\rangle$. In the Schrödinger picture, $A$ does not change, so the base kets, obtained as the solutions to this ...
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### Infinite square well and Heisenberg picture

The infinite square well is often a mainstay of introductory quantum physics courses. Its boundary conditions at the well-walls are easily solved to the find the Hamiltonian's eigenfunctions in the ...
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### How do I add decoherence to an oscillating system

If a have an initial (two-qubit) system in the state $\rho_i= \begin{pmatrix} 0&0&0&0\\ 0&1&0&0\\ 0&0&0&0\\ 0&0&0&0 \end{pmatrix}$ and this state ...
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### Is there a unitary transformation such that the Hamiltonian in the time-dependent Schrödinger equation becomes real symmetric?

The time-dependent Schroödinger equation is given as (with $\hbar=1$): $$i\dfrac{d}{dt}\psi(t)=H(t)\psi(t)\ ,$$ where $\psi$ is some normalized column vector and $H(t)$ is a Hermitian matrix with time-...
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### Time evolution of eigenstates superposition

If a system is in a state $\psi$ which is superposition of, let's say two, energy eigenfunction, namely $\psi_1$ and $\psi_2$, so that $$\psi(t)=\psi_1e^{-i\omega_1t}+\psi_2e^{-i\omega_2t}$$ (I am ...
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### QM: Time evolution with $H = H(t)$

In order to calculate time evolution in QM we use Schrödinger equation \begin{align*} i \partial_t |\psi\rangle_t = H(t) | \psi\rangle_t. \end{align*} If $H\neq H(t)$ then \begin{align*} i \partial_t ...
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### Definition of Hamiltonian in Quantum Mechanics [duplicate]

Is there any particular reason that the Hamiltonian operator was defined in quantum mechanics to be $$\hat H := \frac{\hat p^2}{2m} + V$$ as opposed to $$\hat H := i\hbar \frac{\partial}{\partial t}?$$...
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### Is the universe ~14 billion years old or that's the farthest photons which reached Earth?

I know that the universe: It's around 13.772 billion years old It expands But it's not clear to me if this is not merely the age of the farthest known photons which reached Earth.
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### Can a second-order Schrödinger equation preserve the norm?

Suppose we lived in a universe in which the Schrödinger equation contains second order time derivatives, $$i\hbar \partial_t^2|\varphi(t)\rangle = \mathbb{H} | \varphi(t)\rangle.$$ Would it be true ...
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### Utility of the Magnus expansion (preserving symplectic form?)

There are (at least) two ways to perturbatively solve a matrix initial value problem: the Dyson expansion and the Magnus expansion To be explicit, suppose you're solving for a density matrix $\rho(t)$...
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### How does a particle know how to behave? [duplicate]

How does a particle know it should behave in such and such manner? As a person, I can set mass is so and so, charge is so and so - then set up equation to solve its equation of motion but who ...
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### Collapse of Wavefunction, and Subsequent Time Evolution

To keep it simple, suppose the system is the well-known particle in a 1D infinite potential well. Suppose the wavefunction is $a|1\rangle + b|2 \rangle + c|3\rangle$, where the $|i\rangle$ are ...
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### Phase of quantum state during propagation

Evolution of quantum state in time can be obtained from the time-dependent Schrodinger equation $$\hat{H} \psi(x,t) = i \frac{\partial}{\partial t} \psi(x,t).$$ For time-independent Hamiltonian, the ...
220 views

### Two Time Correlation function calculated from Born rule

Update Below I'm having a hard time reconciling two different calculations of the quantum two time correlation function. Consider quantum operator $A$ with eigenvectors $\{|\phi_i\rangle\}$ and ...
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### Time evolution of a projected mixed state

Suppose a quantum system (non-interacting) at finite temperature ($\beta^{-1}$). I want to know how to compute the transition probability between two degrees of freedom ($u$ and $v$) at two different ...
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### Plausibility of Heisenberg equation for the canonical momentum:

In this question, I want to to know wether my reasoning on the plausibility of the Heisenberg equation is flawed: Let's say I want to describe my system in the quantum-mechanics framework: ...
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### Time evolution of probability in the Heisenberg Picture

How does the probability of a system being in a state change with time in the Heisenberg picture if the state vector is time independent?
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### Is it an assumption or truth for spatial and temporal variables separation if Hamiltonian is time-indepdent in Schrodinger equation?

For the derivation from time-depdent Schrodinger equation to time-indepdent Schrodinger equation, if the Hamiltonian is time-indepdent, we assume the spatial and temporal variables in the wave-...