# All Questions

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### Dyson Series Iteration - Gives Exact Solution?

When we derive the Dyson series for usage as the time evolution operator in the case of a time dependent Hamiltonian, we start with the equation: \begin{align}\hat{U}_I(t,t_i) = 1 - \frac{i}{\hbar}\...
27 views

### Probability density of time-dependent wave functions

Why is it so that probability density of eigenfunctions of time-dependent schrodinger equation are time independent while that of general wave functions (which are a combination of the eigenfunctions) ...
699 views

### Do atomic orbitals “pulse” in time?

I understand that atomic orbitals are solutions to the time-independent Schrödinger equation, and that they are are analogous to standing waves ("stationary states"). However, even a standing ...
41 views

### Wave function of a particle under $V(x)$ (QM)

Suppose I have a particle with mass $m$ and it's under potential of a certain $V(x)$. (NOT an infinite or finite potential well) Also given is the wave function at time $t=0$, $\psi(x,0)$. What is ...
41 views

### Discrete time evolution in a non-Euclidean space?

The time independent schrödinger equation can be written as $$i\frac{\partial \psi}{ \partial t}=H\psi$$ if we consider the case of a 1D particle we can evolve it in time by discretising the ...
96 views

### Wave function evolution of an electron [closed]

In many basic quantum mechanics books the wave packet of an electron is described. It will say that the wave packet will broaden as time evolves because of dispersion. But suppose the electron just ...
118 views

### Why do wavefunctions for stationary states include $e^{-iEt/\hbar}$? [duplicate]

Stationary states are separable solutions with $\Psi(x, t)=\psi(x)e^{-iEt/\hbar}$. But why is that there? Griffiths (Section 2.1 Stationary states, equation 2.8) says that observables for these states ...
230 views

### Does the Schrodinger wave function associated with a non-moving free particle change in time?

I'm a bit confused by an answer given on this question. In the answer with the animation of a moving free (chargeless) particle and a non-moving free particle (or a free particle with a non-zero ...
129 views

### Time evolution of a free particle with a given initial state [closed]

My homework problem reads: Consider a free particle in one dimension. Write an expression for the wavefunction $\psi(x, t)$ given an initial state $\psi_0(x) = Ae^{-ax^2}$ at $t = 0$, where $A$ is ...
63 views

### “General” for time evolution of quantum state

I am reading a book in which at some point they find the time-evolved wavefunction $\phi_0(\mathbf{r},t)$ from the static $\phi_0(\mathbf{r})$. They say that "employing the Heisenberg time evolution ...
222 views

### What's the time derivative of the Annihilation operator?

I've been dealing with annihilation operator recently where you can see related information Time derivative of the state vector as expressed in abstract Hilbert space vs. as a wavefunction How to ...
72 views

### What is the state of particle at time $t$ if at $t=0$ it is in an eigenstate of $\hat{A}$, and $\hat{A}$ commutes with $\hat{H}$?

EDIT: added (assuming $\lambda$ to be non-degenerate). Based on the specifics of the question, we don't in fact know whether this is the case, so it may be that $\left|\lambda\right>$ is not an ...
143 views

### Solving the Schrodinger equation with a time-dependent Hamiltonian

I am trying to find the general solution to the Schrodinger equation with a time-dependent Hamiltonian: $$i \frac{\partial}{\partial t}| \psi(t) \rangle = H(t) | \psi(t) \rangle.$$ My Hamiltonian ...
848 views

### How do base kets satisfy Schrödinger's equation in Schrödinger picture and why don't they evolve with time?

According to Sakurai, eigenvalue equation for an operator $A$, $A|a'\rangle=a'|a'\rangle$. In the Schrödinger picture, $A$ does not change, so the base kets, obtained as the solutions to this ...
146 views

### Infinite square well and Heisenberg picture

The infinite square well is often a mainstay of introductory quantum physics courses. Its boundary conditions at the well-walls are easily solved to the find the Hamiltonian's eigenfunctions in the ...
192 views

### Is there a unitary transformation such that the Hamiltonian in the time-dependent Schrödinger equation becomes real symmetric?

The time-dependent Schroödinger equation is given as (with $\hbar=1$): $$i\dfrac{d}{dt}\psi(t)=H(t)\psi(t)\ ,$$ where $\psi$ is some normalized column vector and $H(t)$ is a Hermitian matrix with time-...
103 views

### Definition of Hamiltonian in Quantum Mechanics [duplicate]

Is there any particular reason that the Hamiltonian operator was defined in quantum mechanics to be $$\hat H := \frac{\hat p^2}{2m} + V$$ as opposed to $$\hat H := i\hbar \frac{\partial}{\partial t}?$$...
267 views

### Can a second-order Schrödinger equation preserve the norm?

Suppose we lived in a universe in which the Schrödinger equation contains second order time derivatives, $$i\hbar \partial_t^2|\varphi(t)\rangle = \mathbb{H} | \varphi(t)\rangle.$$ Would it be true ...
75 views

### Is it an assumption or truth for spatial and temporal variables separation if Hamiltonian is time-indepdent in Schrodinger equation?

For the derivation from time-depdent Schrodinger equation to time-indepdent Schrodinger equation, if the Hamiltonian is time-indepdent, we assume the spatial and temporal variables in the wave-...
207 views

### Is there an equivalent to the Schrodinger equation for quantum mechanics over the reals?

Many people have considered alternatives to standard quantum mechanics in which the Hilbert space is over the real instead of the complex numbers - see e.g. here, here, here, here, here, and here. In ...
77 views

### A fundamental question about Time-dependent Hamiltonians

I have a fundamental question about Quantum Mechanics or even mechanics in general. I am aware that there are stationary solutions and non-stationary solutions. The stationary solutions solve ...
189 views

### Integral of Schrodinger equation for a time-dependent Hamiltonian

I am given the following Hamiltonian, $H=H_1=\frac{p^2}{2m}+\frac{1}{2}m\omega_1^2x^2$ for $t<0$ and $H=H_2=\frac{p^2}{2m}+\frac{1}{2}m\omega_2^2x^2$ for $t\geq 0$. Now I want to integrate my ...
42 views

### State of a system at previous time

If I am given the state of a quantum system at $t=0$ as $| \psi \rangle$ and I know the Hamiltonian $H$ of the system for time $t<0$, how can I write the state of the system at some time $t<0$?
26 views

2k views

### Why is the momentum-space wavefunction for a free particle not a function of time?

Suppose the initial wave function of a free particle is given by $\psi(x,0)$. Now to find how the wave function evolves with time we generally do the Fourier transform of the wave function at $t=0$. ...
138 views

### Origin of the Schrodinger equation by L. D. Landau and E. M. Lifshitz

In the book "Quantum Mechanics" by L. D. Landau and E. M. Lifshitz, it is mentioned that, "The wave function Ψ completely determines the state of a physical system in quantum mechanics. This means ...
391 views

### Is it possible to study a time-dependent Hamiltonian in Schrödinger picture?

Operators in Heisenberg picture are time-dependent while those in Schrödinger picture are time-independent, and they are related by $$A_H(t)=U^\dagger(t,t_0)A_S(t_0)U(t,t_0)$$ where $U(t,t_0)$ is the ...
917 views

### Schrödinger equation for time dependent Hamiltonian and conjugation

The Schrödinger equation for the evolution operator reads: $$\frac{\partial U}{\partial t} = -\frac{i}{\hbar}HU$$ where for a time dependent Hamiltonian which need not commute with itself at ...
38 views

### Time-evolution of localised particle [duplicate]

I am interested in the question of, if a particle is initially localised at some position $x_0$ what it will evolve to at a later time assuming a free Hamiltonian $H = p^2 /2m$. Long story short, I ...
2k views

### Why is time-evolution operator unitary?

When we shift the system's time from $t=0$ to $t = t$, we can define the following operator $\hat{U}$. $$\hat{U} = e^{- i \hat{H} t / \hbar} \, .\tag{1}$$ So many (as far as I read, almost all of) ...
814 views

### Why do we search for stationary solutions to the Schrodinger equation for potential wells?

When considering potential wells textbooks simply say that we search for the stationary solutions of the schrodinger equation. Why do we do this? What tells us that the wavefunction will be ...