Step 1: Explosion is when the materials inside a containing entity, are extremely densely packed, leading to an extremely high pressure difference. Why? The pressure difference is created, as for blowing into balloons, because the balloon membrane has a limiting maximum ability to stretch, beyond which, if stretch, it tends to prevent the stretching. This is because of the interparticle force of attraction between membrane particles, this will resist the entry of more air. If forcedly blown, the membrane is bound to burst because the outward force exerted by the air simply exceeds the inward force by membrane, which can neither expand.
Implosion is the exact opposite, due to which, for example, the submarines taken into great depth cannot contract in size despite inward force by water particles being terribly high. Imagine you take an inflated balloon to the Mariana Trench. As you go down, the balloon slowly shrinks, but if it could not contract in size, it would right away implode below a certain depth.
Thus explosion or implosion depends on two major factors: pressure difference and the resistance of the object to pressure (rigidity).
Step 2: If we place the same balloon in space, the outer pressure due to microgravity, is nearly zero. But the difference in pressure — is it high?
If the theory was true, earth would have exploded already. But it does not because the earth itself pulls everything towards itself. Even if we ignore the gravitational force of every particle / object in theoretically pure space, if you simply release it there without putting the high pressure difference, it won't explode, but only slightly expand.
But it can indeed explode. In your vacuum–exhausted room, the room is very rigid. Also there is no question of pressure difference in the way we look at balloons. In balloon, we have a membrane separating microgravity and high density matter. Here the membrane would be the surface particles, and the pressure difference would be higher than in balloon, but still it would implode into the vacuum because of 2 reasons: (i) the rigidity is higher than the balloon membrane, (ii) the balloon was filled with gas, exerting gas pressure due to "continuous collision between each and every gas particle". But is it same for the particles of our walls? Our walls were filled with minuscule air spaces during formation and same here. Our walls are solid, and the particles inside are not actively hitting each other with the same velocity as the gas in here (here means our case).
What about the object you placed inside? Whether it explodes, depends on the factors I have mentioned before Step 2.
BTW, here's a question for pondering: If the object you place be a hollow balloon (which you have somehow created), what will happen?
Remember, a very dense matter enclosed by a soft membrane in vacuum, will not explode, until it is the collisions of the matter (Kinetic Energy) that forces explosion. In real life, there would be very small expansion, but there would be no explosion.