I am editing this question after the answers are posted just to present my question a little clearly (without changing the main theme of the question). Moreover, this question is solely about flat spacetime and special relativity!
According to the principle of special relativity, "The laws of physics must have the same form under transformations from one inertial frame to another inertial frame".
Lorentz/Poincare transformations are linear transformations from one set of Cartesian coordinates to another set of Cartesian coordinates related by rotations, boosts and/or space-time translations. If the first set is inertial, the second set related to the first by Poincare transformation is also inertial. Under this transformation laws of physics indeed remain the same.
Now, nonlinear transformations from Cartesian to curvilinear coordinate systems (say, Cartesian to Spherical), are still transformations from inertial to inertial, I think. But under Cartesian to curvilinear transformation, the form of the equation does not maintain form invariance as postulated by SR! See comment by Nikos M.
So my question is (the main question), does the above postulate of SR exclude nonlinear transformations from Cartesian to curvilinear coordinate systems? If you say 'yes', then we are using the word 'inertial' in a very restricted sense.
On the other hand, if you say 'no', laws of physics in SR are also form-invariant under nonlinear coordinate transformations (though I need to understand, in what sense), why is the group of Poincare transformations called the only symmetries of physical laws in flat spacetime?