The full information about all properties of (free) electrons and positrons is "stored" in the (quantum) field operator $$\psi(x) =\sum\limits_s \int d\mu(p) \left[ b(p,s) u(p,s) e^{-ip\cdot x}+ d(p,s) v(p,s) e^{i p\cdot x} \right], \tag{1} \label{1}$$ being always "present" at any time-space point $x=(t, \vec{x})$ and independently of the actual state of the system (e.g. vacuum = no particle present, one electron present, one positron present, 153 electrons and 2 positrons present, and infinitely more possibilities).
Although the fermion field operator \eqref{1} is not directly observable, the operators representing the measurable quantities of the system (observables) are obtained from \eqref{1} by building (bosonic) functionals like $$Q= -e\int d^3x\, : \psi^\dagger(x) \psi(x): \tag{2} \label{2}$$ for the charge or $$P^\mu =\int d^3x : \psi^\dagger(x) i \partial^\mu \psi(x): \tag{3} \label{3}$$ for the total energy $P^0$ and the total momentum $\vec{P}$.
If a certain (pure) state $| \chi\rangle$ (out of the infinitely many possible ones) of the system is realized, the expectation value of an observable $A$ is obtained by computing $\langle \chi |A|\chi \rangle$. Let us take the most general one-electron state $$|\chi\rangle = \sum\limits_s \int d\mu(p) f(p,s) b^\dagger (p,s) |0\rangle \tag{4} \label{4}$$ as an example. In this case, we have $\langle \chi |Q |\chi \rangle =-e$ and $\langle \chi |P^\mu |\chi \rangle = \sum\limits_s \int d\mu(p) |f(p,s)|^2 p^\mu$, and analogously for other observables.