How to derive following thermodynamic relation?

Question

I'd would like to derive the following

$$\bigg(\frac{\partial U}{\partial V}\bigg)_T = T \bigg(\frac{\partial p}{\partial T}\bigg)_V - p$$

What I know is that the internal energy $U$ is a function of temperature and volume. Hence, a small change in $U$ can be related to changes in $T$ and $V$ by

$$dU =\bigg(\frac{\partial U}{\partial T}\bigg)_V dT + \bigg(\frac{\partial U}{\partial V}\bigg)_T dV$$

But I'm not sure where to go from here.

Answer 1

Hints:

1. The First Law is $dU = TdS - PdV$.

2. Write $S$ as a function of $T$ and $V$ and take its differential.

3. Use a certain Maxwell relation.