Consider a non-degenerate operator $\Omega$ with discrete eigenvalues $\omega_i$, where $i=1,2,3,...$. We can write $\Omega = \sum_i \omega_i~|\omega_i\rangle \langle \omega_i|$, where $|\omega_i\rangle$ are the normalized eigenvectors. Any arbitrary state may then be expanded as: $|\psi\rangle = \sum_j c_j~|\omega_j\rangle$, where $|c_j|^2$ gives the probability that the state will collapse to $|\omega_j\rangle$ if the measurement corresponding to $\Omega$ were to be performed.
Also the action of $\Omega$ on a state vector yields a new state vector: $$|\psi '\rangle = \Omega |\psi\rangle = \sum_{i,j}\omega_ic_j~|\omega_i\rangle \langle \omega_i|\omega_j\rangle = \sum_{i,j}\omega_ic_j~|\omega_i\rangle \delta_{ij} = \sum_{i}\omega_ic_i~|\omega_i\rangle.$$ The probability that this new state will collapse to $|\omega_i\rangle$, if the measurement $\Omega$ were to be performed, is proportional to $|\omega_ic_i|^2$. The probabilities have now become a function of the possible values for the operator $\Omega$. If operated on by some other operator $\Lambda$ then the probabilities will become a function of its eigenvalues $\lambda_i$, and so on.
I have two questions:
(1) Is my conclusion derived above correct?
(2) What is the difference between an operator that changes the state of a system in general and an operator that corresponds to a measurement? Of course, a measurement also changes the state of system but this change is specific: A measurement always transforms a state vector into one of its eigenstates. This can't be represented mathematically (correct me if I am wrong) because $\Omega |\psi\rangle\neq$ an eigentstate of $\Omega$ (in general).