For simplicity (and for easier drawing) let us
first consider a metric in 2-dimensional space
instead 4-dimensional space-time, i.e.
$$g_{\mu\nu}=\begin{bmatrix} g_{11} & g_{12} \\ g_{21} & g_{22} \end{bmatrix}$$
Now consider a unit-parallelogram in this 2-dimensional space,
with both its coordinate differences $=1$.
It has side lengths $a$ and $b$, and an angle $\theta$ between the two sides.
Then, according to the law of cosines,
the diagonal $\Delta s$ of this unit-parallelogram is given by
$$(\Delta s)^2=a^2+b^2+2ab\cos\theta$$
For a general parallelogram (with arbitrary coordinate
differences $\Delta x_1$ and $\Delta x_2$) its diagonal length $\Delta s$
is given by
$$(\Delta s)^2=a^2(\Delta x_1)^2+b^2(\Delta x_2)^2+2ab\cos\theta\ \Delta x_1\ \Delta x_2$$
That means the metric is
$$g_{\mu\nu}=\begin{bmatrix} g_{11} & g_{12} \\ g_{21} & g_{22} \end{bmatrix}
=\begin{bmatrix} a^2 & ab\cos\theta \\ ab\cos\theta & b^2 \end{bmatrix}$$
which gives you the geometric meanings of all the metric components.
Now you can repeat this reasoning in 3-dimensional space
(using a parallel-epiped instead of a parallelogram)
or in 4-dimensional space-time.
The diagonal metric components $g_{ii}$
give the square of the length of the unit-parallel-epiped
in $x_i$ direction.
And the off-diagonal metric components $g_{ij}$ are related
to the angle between the $x_i$ and $x_j$ direction.
- $g_{ij}=0$ : they are orthogonal,
- $g_{ij}>0$ : there is an acute angle ($<90°$) between them,
- $g_{ij}<0$ : there is an obtuse angle ($>90°$) between them.