Can we say the ability of computers to make decisions is based on a quantum property ?
No. A digital computer is an implementation of logic circuits which embody Boolean logic, a mathematical model which is completely deterministic - the output of each operation is entirely determined by its inputs. Even the pseudo-random numbers provided in many programming languages are actually calculated by a deterministic algorithm.
The only exception to this is if you have a computer that uses a hardware random number generator which generates "true" random numbers from some environmental process. Only in this case can you say that the output of the computer is intentionally based on a quantum property. In all other cases, if the output of the computer is not deterministic then it is because the computer is malfunctioning. Indeed, a lot of the difficulty of designing chips with a very high density of components lies in avoiding any quantum effects that would make the output of the chip non-deterministic.
The occurrence of PN junctions in semiconductor transistors etc. is not an essential part of digital computer design. As has been pointed out in the comments, both mechanical and electronic digital computers were being designed and built long before semiconductor devices were available.
(Note that for the purposes of this answer I am excluding quantum computers, since the quantum gates on which they are built are more akin to analogue devices than digital devices.)