In this question, the answer by twistor59 says
by using the exponential map on linear combinations of [the lie algebra basis vectors], you generate (at least locally) a copy of the Lie group.
I'm interested in the details of "at least locally": Given a fixed basis $A_1, A_2, ... A_k$ of the lie algebra, under what conditions can every element of the lie group be obtained as:
$$ \exp(A_1 a_1 + A_2 a_2 + ... + A_k a_k)\tag{1}$$
and in what cases can it be represented as
$$ \exp(A_1 a_1) \cdot \exp(A_2 a_2) \cdot ... \cdot \exp(A_k a_k) ~?\tag{2}$$
If the $A_i$ commute, $[A_i, A_j] = 0 \;\; \forall i , j $, then the two forms are of course equivalent, and by adding up infinitesimal steps, either of the two forms should be valid, so this question is about the remaining cases.
The last answer here by Arnold Neumaier seems to have an answer, but since it has only one upvote: Can anyone confirm it and / or give more details on how he concludes the following:
If $G$ is a simply connected Lie group with associated Lie algebra $g $, any basis of $g$ is referred to as a (minimal) set of generators of both $G$ and $g$. Indeed, the elements of $g$ are generated by taking linear combinations of generators, while the elements of $G$ are generated by taking products of exponentials $e^{\alpha A_i}$ with real or complex $α$ and a generator $A_i$ . In the compact case, the elements $G$ are also generated by taking all exponentials $e^{∑_i α_i A_i}$.
I have limited background in Lie groups/algebras, so I'm for example not entirely sure about 'simply connected' (for me this means every element is connected to every other element by a path through the lie group, and there are no holes), or 'compact' (to me that means limit points are also contained in the Lie group).