# What is the origin of elements heavier than iron?

In all the discussions about how the heavy elements in the universe are forged in the guts of stars and especially during a star's death, I usually hear that once the star begins fusing lighter atoms to produce iron (Fe) that's the end of the star's life and the whole system collapses onto itself; and based on how massive the star was initially, it has different outcome - like a white dwarf, a neutron star or a black hole.

I have rarely heard a detailed explanation of how the elements heavier than iron are produced. I would appreciate a convincing explanation of this process.

Elements heavier than iron are produced mainly by neutron-capture inside stars, although there are other more minor contributors (cosmic ray spallation, radioactive decay). They are not only produced in stars that explode as supernovae. This has now been established fact since the detection of short-lived Technetium in the atmospheres of red giant and AGB stars in the 1950s (e.g. Merrill 1952), and it is tiresome to have to continue correcting this egregious pop-sci claim more than 60 years later.

The r-process

Neutron capture can occur rapidly (the r-process) and this process occurs mostly inside and during supernova explosions (though other mechanisms such as merging neutron stars have been mooted). The free neutrons are created by electron capture in the final moments of core collapse. At the same time this can lead to the build up of neutron-rich nuclei and the decay products of these lead to many of the chemical elements heavier than iron once they are ejected into the interstellar medium during the supernova explosion. The r-process is almost exclusively responsible for elements heavier than lead and contributes to the abundances of many elements between iron and lead.

There is still ongoing debate about the site of the primary r-process. My judgement from a scan of recent literature is that whilst core-collapse supernovae proponents were in the majority, there is a growing case to be made that neutron star mergers may become more dominant, particularly for the r-process elements with $$A>110$$ (e.g. Berger et al. 2013; Tsujimoto & Shigeyama 2014). In fact some of the latest research I have found suggests that the pattern of r-process elemental abundances in the solar system could be entirely produced by neutron star mergers (e.g. Wanajo et al. 2004), though models of core-collapse supernovae that incorporate magneto-rotational instabilities or from rapidly-rotating "collapsar" models, also claim to be able to reproduce the solar-system abundance pattern (Nishimura et al. 2017) and may be necessary to explain the enhanced r-process abundances found in some very old halo stars (see for example Brauer et al. 2020).

Significant new information on this debate comes from observations of kilonovae and in particular, the spectacular confirmation, in the form of GW170817, that kilonovae can be produced by the merger of two neutron stars. Observations of the presumably neutron-rich ejecta, have confirmed the opacity signature (rapid optical decay, longer IR decay and the appearance of very broad absorption features) that suggest the production of lanthanides and other heavy r-process elements (e.g. Pian et al. 2017; Chornock et al. 2017). Whether neutron star mergers are the dominant source of r-process elements awaits an accurate assessment of how frequently they occur and how much r-process material is produced in each event - both of which are uncertain by factors of a few at least.

A paper by Siegel (2019) reviews the merits of neutron star merger vs production of r-process elements in rare types of core collapse supernovae (aka "collapsars"). Their conclusion is that collapsars are responsible for the majority of the r-process elements in the Milky Way and that neutron star mergers, whilst probably common enough, do not explain the r-process enhancements seen in some very old halo stars and dwarf galaxies and the falling level of europium (an r-process element) to Iron with increased iron abundance - (i.e. the Eu behaves like "alpha" elements like oxygen and neon that are produced in supernovae).

The s-process

However, many of the chemical elements heavier than iron are also produced by slow neutron capture; the so-called s-process. The free neutrons for these neutron-capture events come from alpha particle reactions with carbon 13 (inside asymptotic giant branch [AGB] stars with masses of 1-8 solar masses) or neon 22 in giant stars above 10 solar masses. After a neutron capture, a neutron in the new nucleus may then beta decay, thus creating a nucleus with a higher mass number and proton number. A chain of such events can produce a range of heavy nuclei, starting with iron-peak nuclei as seeds. Examples of elements produced mainly in this way include Sr, Y, Rb, Ba, Pb and many others. Proof that this mechanism is effective is seen in the massive overabundances of such elements that are seen in the photospheres of AGB stars. A clincher is the presence of Technetium in the photospheres of some AGB stars, which has a short half life and therefore must have been produced in situ.

According to Pignatari et al. (2010), models suggests that the s-process in high mass stars (that will become supernovae) dominates the s-process production of elements with $$A<90$$, but for everything else up to and including Lead the s-process elements are mainly produced in modest sized AGB stars that never become supernovae. The processed material is simply expelled into the interstellar medium by mass loss during thermal pulsations during the AGB phase.

The overall picture

As a further addition, just to drive home the point that not all heavy elements are produced by supernovae, here is a plot from the epic review by Wallerstein et al. (1997), which shows the fraction of the heavy elements in the solar system that are produced in the r-process (i.e. an upper limit to what is produced in supernovae explosions). Note that this fraction is very small for some elements (where the s-process dominates), but that the r-process produces everything beyond lead.

A more up-to-date visualisation of what goes on (produced by Jennifer Johnson) and which attempts to identify the sites (as a percentage) for each chemical element is shown below. It should be stressed that the details are still subject to a lot of model-dependent uncertainty.

• Is there any reason to believe that supernovae stopped at element 92, or even 118? I know there are limits to how large a nucleus can get, but I would think that a supernova would be a lot more powerful than any of the reactors we've used to create trans-uranics. Nov 5 '14 at 0:48
• @supercat Sorry for not spotting this earlier. I believe all the stable elements beyond lead are produced almost exclusively in supernova explosions via the r-process. The question about the limits on nuclear size is a different one - possibly already answered on Physics SE - but governed by the properties of the strong, weak and electromagnetic forces. Very heavy and exotic elements may exist briefly in the cores of supernovae before they explode and are probably still present in the crusts of neutron stars. Nov 20 '14 at 12:31
• @JimsBond I am aware of the work (or at least the press release, - the accompanying peer-reviewed journal article does not mention gold once!). There is a body of work though that suggests the very heavy r-process elements are prmarily produce din neutron star mergers. I will update a bit. Jul 14 '15 at 13:08
• @Sean Stable enough that we can measure their cosmic abundances (U, Th). Long lived, would have been a better phrase. Mar 19 '19 at 7:19
• I've seen two recent NOVA documentaries that still state that "all elements heavier than iron are created in Supernovae"! You're right that it would be great if this were described even slightly more accurately. Jan 2 '20 at 3:10

Elements heavier than iron are only produced during supernovae; in these extreme energetic conditions atoms are bombarded by a very large number of neutrons. Rapid successive neutron capture, followed by beta decay, produces the heavier atoms. See http://en.wikipedia.org/wiki/Supernova_nucleosynthesis.

• Your first sentence is totally incorrect. Oct 13 '14 at 21:08
• Elements heavier than iron are also produced in neutron star collisions. It's speculated that most of Earth's gold came from neutron star collisions
– Jim
Jul 14 '15 at 12:40

Inside a star there are two primitive force competing with each other. 1st is the gravitational force which attracts the star's mass towards its core and shrinking the star, due to which the temperature and pressure increases and nuclear fusion stars which releases energy applying a outward radiation pressure (IInd force) balancing the gravitation force and saves the star from shrinking and exploding. No star has enough pressure and temperature to convert the nucleus of iron into further elements (by nuclear fusion). So the nuclear fusion inside the star stops. The gravitational force overcomes the radiation pressure and the star shrinks and explodes known as supernova explosion and that explosion has enough Temperature and Pressure to form all the further nuclei from iron. 90% of the star's masses gets distributed in space (Starting of a new universe) and the remaining 10% mass forms a neutron star (having no charge).

• This is not a detailed enough answer. How are the heavier elements formed at high temp. and pressure? Sep 19 '15 at 22:26