Just wanted to follow up with some insights. I believe that I was mistaken -- your last question is best answered using techniques outside of the method of images. This is, to the best of my knowledge, correct, but a subject-matter expert should probably verify this. I want to know if I'm right, too, so consider reposting the last question only.
Consider a hollow spherical conductor of inner radius $R_A$ and outer radius $R_B$. A charge $q$ is placed in the center, and a conductor is given a potential $V$. There are three regions to consider: inside the conductor, the conductor itself, and outside the conductor. Our goal is to find the potential in the three regions.
The solution inside the conductor is trivial: $V_{II}=V_0$.
The potential inside of the spherical cavity is calculated by the method of superposition. The potential due to the charge itself is $\frac{q}{4\pi\epsilon_0}\frac{1}{r}$ while the potential due to the two surface charge densities ($\sigma_A$ and $\sigma_B$) is a constant. Thus:
$$V_{I}=\alpha+\frac{q}{4\pi\epsilon_0}\frac{1}{r}$$
The potential is continuous at $r=R_a$ (it equals $V_0$ there), and we can use this to eliminate $\alpha$. Thus:
$$V_{I}=V_0+\frac{q}{4\pi\epsilon_0}\left(\frac{1}{r}-\frac{1}{R_A}\right)$$
This equation seems right to me, since the boundary condition holds and it seems to satisfy Poisson's equation:
$$\nabla^2V=\frac{q}{4\pi\epsilon_0}\nabla^2 \frac{1}{r}=\frac{q}{4\pi\epsilon_0}\left(-4\pi\delta^3(\mathbf{r})\right)=-\frac{q }{\epsilon_0}\delta^3(\mathbf{r})=-\frac{\rho}{\epsilon_0}$$
The charge density at $r=R_A$ can be derived from the following equation in Griffiths Introduction to Electrodynamics (Third edition, Section 2.3.5):
$$\nabla V_{above}(R_A)-\nabla V_{below}(R_A)=-\frac{\sigma_A}{\epsilon_0}\mathbf{\hat n}$$
I'll spare you the details, but I get
$$\sigma_A=-\frac{q}{4\pi R_{A}^2}$$
As it turns out, the charge distribution on the inner surface does not depend on the applied potential. Additionally, you can see that the total induced charge on the inner surface is $-q$, just enough to completely neutralize the inner charge.
The potential outside of the sphere can be derived by considering the following general solution given by Griffiths (Third Edition, Section 3.3.2, Example 3.7):
$$V=\sum_{l=0}^\infty \left(A_l r^l + \frac{B_l}{r^{l+1}} \right)P_l(\cos{\theta})$$
As before, I'll spare you the details, but it turns out that
$$V_{III}=\frac{R_B V_0}{r}$$
The surface charge density on the outer surface can be derived as before. I get
$$\sigma_B=\frac{\epsilon_0 V_0}{R_B} $$
This seems to make sense -- if the sphere is grounded, then no charge will be induced. And as $V_0$ increases, the induced charge increases.
I'm sure that others can give a 2-sentence argument for why the above had to be true intuitively, but there it is, a priori.