You can’t know that at a certain time there will be a radioactive decay. You can say that the decay will occur with a certain probability, but never with a certainty.
Even if the decay happened at a certain time $t$, if you could hypothetically roll back the universe$^1$ and then let it continue, there is no guarantee that the same decay will happen at the exact same time. This is exactly what we mean when we say that quantum mechanical processes (like radioactive decay) are not deterministic$^2$.
At the quantum level, all processes have an inherent uncertainty and there is no way around this. It is an intrinsic property of nature.
$^1$ For the same reasons, this would be impossible even in principle. If you could do such a thing, this would imply that the universe is deterministic, and for the reasons discussed, it certainly is not.
$^2$ Note that determinism is considered to depend on the interpretation of quantum mechanics. I more or less refer to the Copenhagen Interpretation (perhaps the most common amongst physicists) whenever talking about QM though I have never given this deeper consideration.
But one of the cornerstones of quantum mechanics, the Heisenberg uncertainty principle (HUP), supports of the notion of the non-deterministic nature of the universe, and this principle is valid in both Copenhagen and other interpretations (although the HUP may itself be interpreted differently in these other interpretations).