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I have read that

when a reaction occurs in which the products of the reaction are in a less energetic state than the reactants, the kinetic energy of the products is increased over that of the reactants. By a less energetic state I mean the electrons (chemical reaction) or nucleons (nuclear reaction) are more tightly bound so the atoms or nuclei of the products have less internal energy than the internal energy of the reactants, and this decrease in internal energy is a decrease in rest mass. In a reaction the total energy E of the products equals that of the reactants. For the reaction, energy is equivalent to mass through $E=mc^2=T+m_0c^2$, where $m$ is the relativistic mass and $T$ is the relativistic kinetic energy; for an exothermic reaction $T$ of the products is greater than $T$ of the reactants and $m_0$ of the products is less than $m_0$ of the reactants. The decrease in rest mass is a decrease in internal energy. The decrease in rest mass is a result of the electrons or nucleons of the products being in a less energetic state (more tightly bound) than the reactants, and energy would be required to restore the internal energy of the products to the internal energy of the reactants. Binding energy is a measure of how tightly bound are the electrons/nucleons and an increase in binding energy is a decrease in rest mass.

Here why being bound decreases the internal energy of the nucleons and if the energy is decreased , it should be of small amount and should be equal to very miniscule amount of mass while energy released as a product of nuclear fusion is humongous... Kindly state the reason why the energy decreases after particles are bound and it should be of small amount while it is large.

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2 Answers 2

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As to your first question, why does the particles being more tightly bound decrease rather than increase their rest mass, think of it this way: when the nucleons are more tightly bound, you need to add energy to the system to force them farther apart. In other words, you need to do work (i.e. expend energy) to pull the nucleons further apart from each other. When you add energy, you add (relativistic) mass.

As to your second question, of course the mass difference for a single atomic reaction is miniscule on macroscopic scales. However, consider the difference between the energy released per fusion reaction (17.6 MeV in the case of DT fusion) and the energy released in a chemical reaction (e.g. burning coal), which is on the order of 1-10 eV per reaction (depending on the substance you are burning etc.). From this you can see that the difference in energy released per reaction is six orders of magnitude - nuclear (fusion, but also fission) releases a million times more energy per reaction than burning something. Scale this up to a fusion reactor where the fuel density is on the order of $10^{20}$ particles/m$^{3}$ in a reactor of several (hundreds of) cubic meters in volume, and you get a very large energy output.

EDIT: in response to Hardik's additional question: There are forces at work here, the strong nuclear force and the electromagnetic force. The way the nucleons are bound are through the strong nuclear force, which easily overcomes the electromagnetic repulsion of the positive protons in the nucleus but only at short distances. So before you can get the reacting nuclei close enough together so that the strong force takes over and binds the nucleons into a new, more tightly bound and therefore lighter particle, you need to do a lot of work to overcome the electromagnetic repulsion. This is why fusion plasmas need to be so hot; the particles need enough kinetic energy to overcome this energy barrier that the electromagnetic force creates. However, once you overcome this barrier, the potential well on the other side, where the strong force takes over, is much deeper than the energy you had to put in to bring the particles close. This is illustrated nicely in this schematic:

In this figure, imagine one particle is sitting at the origin on the left, while the other particle approaches from the right. You need to put in an amount of energy equal to the shaded purple area to get the right particle over the Coulomb barrier, but then it falls into the strong force potential well which releases the shaded green area of energy, which is greater than the shaded purple area because the well is so deep (the strong force is so much stronger than the electromagnetic force). This is the energy that is released in a fusion reaction.

EDIT 2: In response to a second additional question: exactly, helium is more tightly bound than deuterium and tritium and the difference is released as energy. This 17.6 MeV is not again going into binding energy because quantum mechanics dictates the binding energies of the reacting particles and the reaction products, so those are fixed. The leftover energy then has to go somewhere else. The I'm not sure exactly what you mean by "free" energy, but this 17.6 MeV of energy is released as kinetic energy of the reacting products. There's simply nowhere else for that energy to go. In other words, the helium and neutron that are generated are given a big "kick" of kinetic energy when they are created in the reaction. That kinetic energy is distributed according to conservation of momentum, so 3.5 MeV to the alpha particle (helium nucleus) and 14.1 MeV to the neutron. If you're wondering why that specific number, it's because the reaction products contain 5 total nucleons (3 neutrons and 2 protons, that have approximately the same mass). The alpha particle contains 4/5th of the nucleons and the neutron has 1/5th, so the energy is distributed so that 1/5*(17.6 MeV) = 3.5 MeV goes to the alpha particle and 4/5*(17.6 MeV) = 14.1 MeV goes to the neutron.

I hope this answers your question(s).

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  • $\begingroup$ But WHY does nuclear fusion release energy? And you stated that we need to expend more energy on tightly bound nucleons. Then in the case of the resultant product nucleus , shouldn't it increase the mass and leading to consumption of energy rather than releasing because nucleons in the resultant nucleus are more tightly bound??... $\endgroup$
    – Hardik
    Feb 4, 2022 at 6:49
  • $\begingroup$ Hi Hardik, please see the edit that I made to my original answer above $\endgroup$
    – JSlief
    Feb 4, 2022 at 9:35
  • $\begingroup$ ,So you mean that nucleons bound in the reactant nuclei have low binding energy and when they fuse together , the nucleons are bound more tightly as coloumb force is also increasing. Since energy is required to tightly bind them , hence mass is converted to energy and this energy is released? If so , shouldn't the energy released used in the binding instead of being released as "free" energy. If no , then what is the reason for the release of energy and mass defect? $\endgroup$
    – Hardik
    Feb 16, 2022 at 4:06
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The fusion energy is huge on the condition of producing a lot of unit fusions. The D+T fusion produces 17.58 MeV. Calculate this value in joules and then calculate how many fusion reactions will be needed for ITER to operate at 400 MW.

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  • $\begingroup$ The cause was the main question stated above....kindly answer that one. $\endgroup$
    – Hardik
    Feb 1, 2022 at 16:34

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