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What kind of matter is positronium? Normal matter, antimatter, exotic matter or something else?

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We know:

Matter is made up of electrons, protons and neutrons.

Antimatter is made up of positrons, antiprotons and antineutrons.

But positronium is made up of an electron and a positron. Where an electron is a normal particle and a positron is an antiparticle. So, how do we classify positronium? As normal matter or antimatter or a hybrid of both?

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    $\begingroup$ Does it matter? $\endgroup$
    – Dale
    Jan 16 at 16:44
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    $\begingroup$ And my question is does it matter? What changes about it if you classify it as matter, or if you classify it as antimatter, or if you classify it as both, or if you classify it as neither. In what way does the classification make a difference? $\endgroup$
    – Dale
    Jan 16 at 16:57
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    $\begingroup$ It's neither matter, nor antimatter: it's self-conjugate matter, like unstable pions. Your dysfunctional definition of matter relies on silly application of baryon and lepton numbers as characterizing "matter", to contrast it to photons, thus classified as "radiation". It is a "lies to children" mirage, designed to confuse, and it succeeded. $\endgroup$ Jan 16 at 19:44
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    $\begingroup$ somewhat related in Chemistry SE What is a "hydrogen-like" or "hydrogenic" atom? $\endgroup$
    – uhoh
    Jan 17 at 11:05
  • $\begingroup$ @Dale ツ. As with many things physical, the words mean different things to different physicists. To a cosmologist, the "matter" of the question is a minor constituent of the "matter" in the universe. "Dark matter" dominates, and is in turn dominated by "dark energy". But calling the latter "energy" is arbitrary, too: it's essentially stuff with a weird equation of state (and no other known properties), unlike anything seen in a laboratory. $\endgroup$
    – John Doty
    Jan 17 at 13:41

4 Answers 4

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You should consider positronium as evidence that your partition of the universe into matter and antimatter is overly simplistic.

You write that

Matter is made up of electron, proton, and neutron.

But that only describes stable matter, and only stable matter that happens to interact with electromagnetism. A census of stable matter should also include the neutrino; we leave it out of chemistry classes because it doesn’t form molecules. (However it is possible that neutrinos indirectly influence the stability of molecules.) An inventory of “electromagnetic matter” should also include the mu and tau leptons, and baryons like the lambda and sigma which contain heavy quarks. If you complain that particles from the second and third generations are exotic because they are unstable … well, the neutron is unstable. Should your list of “matter” be “electrons, protons, and nuclei”? Do unstable nuclei like tritium and carbon-14 count as “normal” matter, or are they “exotic” until they decay into helium-3 or nitrogen-14? (And of course those decays send an anti-neutrino off in the process, to be someone else’s classification problem.)

In order to compute the energy eigenstates of positronium, and their properties like spin, parity, and lifetime, we use the same tools that intro-quantum students use to describe the hydrogen atom. So in the “quacks like a duck” sense, it makes sense to call positronium an “atom.” Because positronium doesn’t really fit on the periodic table, and because it doesn’t make a big contribution to chemistry, you might call it an “exotic” atom.

But “exotic” might give you the mistaken impression that positronium is uncommon or hard to find, in the same way that I’m probably never going to encounter a rhinoceros or a scarlet macaw unless I make some special arrangements. That’s not really the case. Formation of positronium is a normal step in the annihilation of fast positrons in matter, and is therefore no less common than positrons. If you are a human person who is partially made of potassium from Earth, you contain positronium many times per hour.

In quantum electrodynamics, we learn that the electron and positron are really excitations of the same field: a four-component spinor with two charge states and two spin states. In a very real sense, positronium is the simplest “matter-ful” state of electromagnetism, and is mathematically simpler than the more familiar state where there are lots of electrons and not very many positrons. This perspective has important physical consequences. The force-carrying photon can be said to “spend part of its time” as a virtual electron-positron “loop.” The loop corrections to electromagnetism are related to observables like the change in the effective electron charge at short distances (more frequently called the “running of the fine-structure constant” due to “vacuum polarization”), as well as corrections to the magnetic moment of an electron at rest.

I disagree with your other answer and your comments that the classification is “duzzit matter” or that your question is silly. That punts on the issue. Near the middle of his excellent Ancestor’s Tale, Dawkins writes about “the tyranny of the discontinuous mind.” Categorizations are extremely useful, he says; but sometimes categorization is impossible, or categories which are useful in one context are useless in another. Recognizing when this has happened is an opportunity to learn interesting things.

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    $\begingroup$ +1 though "In quantum electrodynamics, we learn that the electron and positron are really excitations of the same field: a four-component spinor with two charge states and two spin states" involves a particular philosophical definition of reality $\endgroup$
    – Henry
    Jan 17 at 11:19
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Wikipedia classifies positronium as an exotic atom. However, since it has a lifetime of (at best) around 100 nanoseconds, the label that we attach to it hardly matters.

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  • $\begingroup$ Exotic atoms and exotic matter are not related concepts. $\endgroup$
    – Xerxes
    Jan 18 at 17:06
  • $\begingroup$ @Xerxes Wikipedia classifies exotic atoms as one form of exotic matter en.wikipedia.org/wiki/Exotic_matter $\endgroup$
    – gandalf61
    Jan 18 at 17:32
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All our elementary particle experiments and observations fit perfectly to the Lorentz framework , a framework where each elementary particle or composite of elementary particles is perfectly described by the four vector $(E,p_x,p_y,p_z)$. The length of this four vector is the invariant mass, $m_0$. All our experimental data and observations show that $m_0$ is larger than or equal to zero, for all known particles and their composites.

My simple answer would be that there is no antimatter as far as our experiments and observations go. There are antiparticles to particles, which have the mirror quantum numbers, but matter which in colloquial parlance defines the mass of classical mechanics is always the same down at the particle level .

This is the confusion, confusing antiparticles with antimatter. The positronium is a composite of a particle and an antiparticle.There are experiments with anti-Hydrogen too, Lorentz transformation hold, and the invariant mass does not differ from the invariant mass of Hydrogen, although the experiments try to find differences from physics beyond the standard model..

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    $\begingroup$ Your definition of antimatter as the material with negative mass seems to be uncommon. The common definition (given e.g. in Wikipedia) is the matter composed of antiparticles, and your example of anti-hydrogen is exactly an example of antimatter. $\endgroup$
    – Ruslan
    Jan 17 at 14:08
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    $\begingroup$ @Ruslan yes, but it is a misleading use of definitions, because the hoi polloi start thinking of negative matter or questions on whether positronium .and antihydrogen are different than normal matter, they are not, they are all made of matter $\endgroup$
    – anna v
    Jan 17 at 14:34
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There are nice answers by @annav and @rob, I would like to add how both electrons and positrons are excitations of the very same field, that permeates all of space, just a manifestation of the same (normal) energy. My favorite example of this is pair creation, where energetic photon(s) transform into (just like in your example) and electron and a positron, both created from the same underlying energy of this quantum mechanical universe.

https://en.wikipedia.org/wiki/Pair_production

Jus like when you pluck a string (you excite a field), you can pluck it many ways, do it one way, you get an electron, pluck it (excite the field) another way, you get a positron, but you just play with the same old field, on the same old guitar (universe).

We happen to live in a universe where dark energy dominates, it is just that in our close surroundings everything is made up of normal energy (matter), and that includes both electrons and positrons, and for this reason by convention only, we call this normal energy (matter), and we call dark energy the other one that dominates overall. Just like this convention, we happen to live in a universe where electrons in our surroundings dominate over positrons, and for this reason only we call electrons matter and positrons anti-matter.

Yes, this 4.6% includes everything we know about except dark matter and dark energy. So it includes atoms, baryons, leptons, neutrinos, antimatter, cosmic rays, and the mass-energy from virtual particles as well (much of the mass of the proton and of atoms comes from that). Depending on your definition of "exotic matter", that's either hypothetical and so everybody's guess, or things like positronium which isn't stable but would be part of those 4.6%

Does Normal matter also include anti-matter and engery?

But the ultimate answer to your question is that positronium (just like quarkonium) is just a manifestation of the same underlying phenomenon, that we call (normal) energy, both electrons and positrons are (slightly different) excitation of the same underlying quantum field.

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