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In the link, Solving Dirac for one electron atom/ion the energy for the one electron $s_1$ shell is calculated as $$ E=m_{\mu}c^2\left( 1 - \frac{1}{\sqrt{1+\left( \frac{\alpha Z}{n-j-1/2 + \sqrt{(j+1/2)^2-\alpha^2 Z^2}} \right )^2}}\right). $$

I am confused because if $Z=92$, then this is not computable for $j=0$ as $\alpha 92 > 1/2$ and then $ \sqrt{(j+1/2)^2-Z^2\alpha^2}$ is imaginary. Why's that? Is the formula in the link wrong?

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  • $\begingroup$ The Klein Paradox: At Large $Z$ the vacuum is unstable to pair creation in which an electron from the filled Dirac sea can tunnel though the potential barrier and occupy the energy lowest state. $\endgroup$
    – mike stone
    Commented Dec 12, 2021 at 22:34
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    $\begingroup$ @mikestone Perhaps but there is no such thing as a filled Dirac sea. $\endgroup$
    – my2cts
    Commented Dec 12, 2021 at 23:51
  • $\begingroup$ @ my2cts Why not? It is convenient way to keep track, and as (these days) a condensed matter theorist it is how I have learned to think of things. The argument about infinite electric charge is misleading. In the standard model each generation has $3\times 2/3 $ up quarks, $-3\times 1/3$ down quarks, and $-1$ electon-like particle, Net vacuum charge for each generation is zero. There is nothing that the filled sea gets wrong. $\endgroup$
    – mike stone
    Commented Dec 13, 2021 at 1:36

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As far as I understand, $j=0$ is impossible as $l=j\pm\frac{1}{2}$. Look at the definitions of $l$ and $j$.

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  • $\begingroup$ Yes that makes sense, using this improves the values for other elements as well $\endgroup$
    – Stefan
    Commented Dec 12, 2021 at 23:03

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