I'm wondering if it's possible to derive energy eigenstates for a fermion field without guessing the anti-commutation relations from the start. I'm taking the Hamiltonian for a Weyl field $\psi$ to be $$ H=\sum_k \sum_s H_{k,s}, \qquad \sum_s H_{k,s} = \psi_k^\dagger (\vec k \cdot \vec\sigma) \psi_k $$ For $\vec k$ and spin aligned with the $z$ axis, this becomes $$ H_{k,+} = k (\psi_{k,1r}^2 + \psi_{k,1i}^2) $$ The conjugate momentum to $\psi_k$ is $ \pi_k = i \psi_k^\dagger$, so the conjugate momenta for the components of $\psi_{k,1}$ would be $$ \pi_{k,1r} + i \pi_{k,1i} = \psi_{k,1i} + i \psi_{k,1r} $$ I assume we need to pick either the real or imaginary component to take as our canonical coordinate, with the other becoming its conjugate momentum. Let's take $\psi_{k,1r}$. $$ \hat H_{k,+} = 2 k \left( \frac12 \hat \pi_{1r}^2 + \frac12 \hat \psi_{1r}^2 \right) $$ The expression in parentheses looks like the Hamiltonian for a harmonic oscillator, which maybe is okay if there's some criterion that excludes all excited states above the first (leaving two states---occupied and unoccupied).
Is the derivation right so far? Or did we need to know ahead of time that $\psi_{k,1r}$ and $\psi_{k,1i}$ aren't like ordinary real numbers---or that $\hat\pi_{k,1r} \not\equiv -i \, \partial/\partial\psi_{k,1r}$?
EDIT: continuing the thread
Now I'm thinking that rather than picking one of $\{\psi_{k,1r},\psi_{k,1i}\}$ as the canonical coordinate, we should recognize that there's an ambiguity and leave it intact. For any $0 \leq \alpha \leq 1$, the Hamiltonian can be decomposed as: $$ \hat H_{k,+} = k \left[ \alpha \left( - \frac{\partial^2}{\partial \psi_{k,1r}^2} + \hat\psi_{k,1r}^2 \right) + (1-\alpha) \left( - \frac{\partial^2}{\partial \psi_{k,1i}^2} + \hat\psi_{k,1i}^2 \right) \right] $$ The eigenstates are then $$ \Psi_n(\psi_{k,1r},\psi_{k,1i}) = \exp(-\tfrac12 (\psi_{k,1r}^2 + \psi_{k,1i}^2)) H_n(\psi_{k,1r}) H_n(\psi_{k,1i}) $$ where $H_n$ are Hermite polynomials---they are products of harmonic oscillator eigenstates with the same energy level. The states also need to respect the global phase symmetry $\psi \to e^{i\phi} \psi$ $$ \psi_{k,1r} \to \psi_{k,1r} \cos\phi - \psi_{k,1i} \sin\phi \qquad \psi_{k,1r} \to \psi_{k,1i} \cos\phi + \psi_{k,1r} \sin\phi $$ This means that after the transformation, the wave function needs to still be an eigenstate of the Hamiltonian (for any choice of $\alpha$. The ground state $\Psi_0$ does respect the symmetry, since $H_0(x) = 1$ and $(\psi_{k,1r}^2 + \psi_{k,1i}^2)$ is invariant.
The first excited state $\Psi_1$ contains an overall factor $\psi_{k,1r} \psi_{k,1i}$, so if we later make a gauge choice $\psi_{k,1i} \equiv 0$, that state would be zero everywhere.