Conductors connected with a wire Let's say I have two spherical conductors with different radii and different amount of positive charge on them. The spheres are far enough from each other. I connect them with a conducting wire. I'm told that the charge is going to flow until both of the conductors gain the same potential (on top/inside of them). Now, intuitively it seems fine but I do not quite understand a few things. 
1) The intuition is that the electric field should be zero everywhere when they reach the same potential, because then the charge is not going to flow. But it is not always the case.
2) Shouldn't the wire also contain some charge after the rearrangement? Because if no, then its potential will be zero, and so there will be a difference in potentials between one of the conductors and the wire, so the charge should still flow into the wire.
I'll try to rephrase the question, because it seems people keep getting my question wrong - in general, I can't understand why charges should always flow until both of the conductors reach the same potential. I mean, the fact that the conductors have same potential doesn't really tell us that the field which drives charges is zero. What's the proof that connected conductors reach the same potential?
 A: 1) At the conductor surfaces, the tangential electric field is zero in equilibrium (otherwise charge would flow).  The normal field need not be zero.
Zero tangential field is equivalent to the surface being an equipotential.  (Potential is, after all, the line integral of the field (times -1).) The fact that the conductors have the same potential really does tell us that the field which drives charges is zero, and vice versa.  If the tangential field is not zero, charges will flow until it is, or equivalently until the surface is an equipotential.
2) Note that a smaller sphere requires less charge than a larger one to achieve the same potential (you can see this by integrating the field from infinity for the two cases).  The wire is really small (in radius), and needs correspondingly even less charge.  In the limit of a 0 radius wire, the required charge goes to 0.
Differing charges do not necessarily imply different potentials.  The capacitance, which depends on the geometry, gives the constant of proportionality between charge and potential.  It's different for different shapes, so, at equal potentials, different shapes will contain different charges.
A: When two charged spheres are joined by wire then charge flows from high potential to lower one until they come to same potential. The sphere larger in size acquires more charge as it has higher capacitance. 
After joining by wire, electric filed will not be zero but electric field will change according to its capacitance and charge shared. At one point electric field of one sphere may be canceled by electric field of another. The point is termed as null point. but other points electric field is not zero being same potential.
Charge distributes on outermost surfaces of spheres so connecting wire only provides path for charge transfer. Finally  no charge resides on it. charges always resides so that potential energy of system remains minimum. To maintain minimum energy the charges always reside on outer surfaces....
A: At equilibrium the electric field inside the spheres and wire must be zero. The charges only on the spheres can not make the electric field zero everywhere in the wire so a charge distribution on the wire is also needed. 
A: It's actually pretty simple. The charges would repel each other and try to be as far as possible. The only way they can do this is by residing in the surface of the spheres
