Suppose we have a Schwarzschild black hole of mass $M$ at a distance $R$ to an observer. Due to the curvature of space, the apparent angle (or half-angle) of occlusion $\theta_a$ of the silhouette of the blackhole will be larger than the angle described by its Schwarzschild radius, $\theta_s$. But how much larger?
Taking no relativistic effects into account, the angle subtended by the center of a sphere to the edge of a sphere with a radius the same size as the Schwarzschild radius $r_s=\frac{2GM}{c^2}$ can be deduced to be $\theta_s=\arcsin\frac{r_s}{R}=\arcsin\frac{2GM}{Rc^2}$. However, a light ray cast from the observer at an even larger angle (maximally $\theta_a$) may find it's way falling into orbit or directly into the blackhole, causing the apparent size of the blackhole to be larger than its Schwarzschild radius.
How is $\theta_a$ described by $R$ and $M$? Is it the angle (or half-angle) subtended by the photon sphere?