First of all, the scaling law is as follows. For a photon detected emitted at $t_0$ and detected at $t_1$ we have the redshift $z$ of the photon given by the scale factors $a$ at times $t_0, t_1$ as
$$\frac{a(t_0)}{a(t_1)} = \frac{1}{1 + z}$$
That is, the redshift is derived from the ratio of scale factors. The issue with confirming this relation is that $a(t)$ is a metric component, and metric components are typically not directly observable. One has to be very careful - what exactly is meant by "testing" the $a-z$ relation? What are the observations that we are comparing?
Let's take a look, the scale factor $a(t)$ is special, since it chosen to correspond to the rescaling of distances in the cosmological comoving frame. The $a-z$ relation could then be taken as a definitory statement, since it really corresponds to the stretching of distances between the wavecrests of the photon. In that case, one would just need to verify the isotropy and other assumptions of the FLRW cosmology to test whether such a definition of the scale factor is self-consistent. This is actually how cosmology is built in practice, astronomers essentially do not refer to $a$, they refer to $z$ and define the cosmological eras using the redshift as a "coordinate".
Another operational definition of $a(t)$ (up to a rescaling) could be also from the average distance between ordinary matter such as galaxies and clusters of galaxies. If one is able to track all the matter in one era and measure its distances, compare this with another era, one essentially finds the ratio of $a(t)$s between these two eras. Does this ratio agree with the redshift observed between them?
Unfortunately, this simple idea is extremely difficult to realise. At short distances you can cover things well but you do not have the statistics (you need Gigaparsec volume averages for FLRW cosmology to start making sense), at larger distances you start having selection effects (for instance, you notice less bright things less). And when you pass between eras with very different redshifts, you have different selection effects for every era: you use different instruments with different capabilities because the wavelengths become different (and you need different sensitivities), and even the objects themselves change, since they may be glowing more or less dependent on the era you are in. In short, there is no good experimental test of a definition of $a(t)$ based on average distances, you have to take the redshift relation as more of a definition.