(This first section refers to v1 of the post)
Now, mathematically what this means is that if we prepare a large number of states $|Ψ⟩$ and perform measurements of the position and momentum on them (not doing >1 measurement on any prepared system)...
First mistake. For example, measuring $X$ on one state gives you a new state, so the resulting $\Delta p$ you get from subsequent momentum measurements will not be related (by the HUP) to the previous $\Delta x$ you obtained.
The HUP is a statement about measurements of $X$ or $P$ separately on a large number of similar states. So, take a large number of similar states and measure $X$ for each one to get $\Delta x$. Take another larger number of similar states and measure their momentum to get $\Delta p$. The HUP says that no matter what state you started with, you will always find $\Delta x\cdot\Delta p$ to be no smaller than $\hbar/2$.
...the RMS value of deviation from the mean for both will show an inverse relationship with each other.
Second mistake. If you have multiple similar states and do the above steps you will get a single $\Delta x$ and a single $\Delta p$. There is no inverse relationship to be found.
However, let's say we were to then take a different state and do the same procedure, and let's say $\Delta x$ is now smaller than before. We still cannot say anything about the new $\Delta p$. $\Delta p$ could increase or decrease; all we would know is that $\Delta x\cdot\Delta p$ can be no smaller than $\hbar/2$. However, if the previous $\Delta x\cdot\Delta p$ was exactly equal to $\hbar/2$, then we could guarantee a larger $\Delta p$ because the HUP must hold.
How then does this lead to a restriction on the individually measured values of position and momentum?
It doesn't. The HUP does not say anything about individual measurements.
How do we make claims such as the particle is restricted to this box so it can't have a zero momentum and so forth?
You can certainly make a $0$ momentum measurement. That doesn't violate the HUP. The HUP would be violated if $\Delta p=0$, i.e., if every momentum measurement of our large collection of similar states gave us the same value every single time.
To address the title then:
Why can't the Uncertainty Principle be broken for individual measurements if it is a statistical law?
As stated above, the HUP does not say anything about individual measurements. It just puts a bound on the product of the "spreads" of two types of measurements.