Intuitive I will also say that you obtain the maximum of the springs deflections at
$~\theta_1=\frac{\pi}{2}~,~\theta_2=\frac{\pi}{2}~$
mathematical proof
\begin{align*}
&\textbf{the generalized coordinates are}\\
&\boldsymbol q=\left[ \begin {array}{c} r_{{1}}\\ r_{{2}}
\\ \theta_{{1}}\\ \theta_{{2}}
\end {array} \right]\\
&\textbf{postion vectors}\\
&\boldsymbol R_1=\left[ \begin {array}{c} \left( L_{{1}}+r_{{1}} \right) \cos \left(
\theta_{{1}} \right) \\ \left( L_{{1}}+r_{{1}}
\right) \sin \left( \theta_{{1}} \right) \end {array} \right]
\\
&\boldsymbol R_2=\boldsymbol R_1+\left[ \begin {array}{c} \left( L_{{2}}+r_{{2}} \right) \cos \left(
\theta_{{1}} \right) \\ \left( L_{{2}}+r_{{2}}
\right) \sin \left( \theta_{{1}} \right) \end {array} \right]
\end{align*}
according to d'Alembert principal you obtain the static equilibrium from this equation
\begin{align*}
&\boldsymbol J^T\,\boldsymbol F=0\qquad\qquad (1)\\\\
&\text{with}\\
&\boldsymbol J=\frac{\partial \boldsymbol R}{\partial \boldsymbol q}
\qquad,\boldsymbol R=\begin{bmatrix}
\boldsymbol R_1 \\
\boldsymbol R_2 \\
\end{bmatrix}\qquad,
\boldsymbol F=\begin{bmatrix}
\boldsymbol F_1 \\
\boldsymbol F_2 \\
\end{bmatrix}\\\\
&\text{and the force components of mass 1 and mass 2 are}\\\\
&\boldsymbol F_1= -m_1\,\boldsymbol g-k_1\,(L_1+r_1)\,\boldsymbol e_1-k_2\,(L_2+r_2)\boldsymbol e_2\\
&\boldsymbol F_2= -m_2\,\boldsymbol g+k_2\,(L_2+r_2)\boldsymbol e_2\\\\
&\text{and}\\\\
&\boldsymbol e_1=\left[ \begin {array}{c} \cos \left( \theta_{{1}} \right)
\\ \sin \left( \theta_{{1}} \right) \end {array}
\right]\qquad,
\boldsymbol e_2=-\left[ \begin {array}{c} \cos \left( \theta_{{2}} \right)
\\ \sin \left( \theta_{{2}} \right) \end {array}
\right]
\end{align*}
hence equation (1)
\begin{align*}
& \boldsymbol J^T\,\boldsymbol F=
\left[ \begin {array}{c} \left( -\sin \left( \theta _{{1}} \right)
m_{{1}}-\sin \left( \theta _{{1}} \right) m_{{2}} \right) g-k_{{1}}L_
{{1}}-k_{{1}}r_{{1}}\\ -k_{{2}}L_{{2}}-k_{{2}}r_{{2}
}-\sin \left( \theta _{{2}} \right) m_{{2}}g\\ -
\left( L_{{1}}+r_{{1}} \right) \cos \left( \theta _{{1}} \right) g
\left( m_{{2}}+m_{{1}} \right) \\ - \left( L_{{2}}+
r_{{2}} \right) \cos \left( \theta _{{2}} \right) m_{{2}}g
\end {array} \right]=0\\
&\Rightarrow\\\\
&\text{from the first two equations you obtain}\\\\
&r_1(\theta_1)=-{\frac {k_{{1}}L_{{1}}+\sin \left( \theta_{{1}} \right) m_{{1}}g+\sin
\left( \theta_{{1}} \right) m_{{2}}g}{k_{{1}}}}\\
&r_2(\theta_2)=-{\frac {k_{{2}}L_{{2}}+\sin \left( \theta_{{2}} \right) m_{{2}}g}{k_{
{2}}}}\\\\
&\text{hence the maxima}\\\\
&\frac{dr_1}{d\theta_1}=0\qquad\Rightarrow~\theta_1=\frac{\pi}{2}\\
&\frac{dr_2}{d\theta_2}=0\qquad\Rightarrow~\theta_2=\frac{\pi}{2}\\
&\Rightarrow\\
&r_1(\pi/2)=-{\frac { \left( m_{{2}}+m_{{1}} \right) g}{k_{{1}}}}-L_{{1}}\\
&r_2(\pi/2)=-{\frac {m_{{2}}g}{k_{{2}}}}-L_{{2}}\\\\\\
&d_{1\text{max}}=r_1+L_1=\bigg|\frac{(m_1+m_2)\,g}{k_1}\bigg|\\
&d_{2\text{max}}=r_2+L_2=\bigg|\frac{m_2\,g}{k_2}\bigg|
\end{align*}