I was wondering if a material existed which opposed applied electric fields, analogously to a diamagnetic material, which opposes magnetic fields. So the flow of charge would be against the field, rather than toward the field. In other words, instead of electrons flowing or atoms polarizing towards a positive electric field, they move away from it and towards the negative, like a diamagnetic material aligning itself against the magnetic field. Maybe a big stretch, but I was wondering if that existed in any form.
Edit: Maybe I was unclear in my description of opposing electric fields. In a dielectric, the atoms and molecules polarize so that the negatively charged parts face the positively charged electrodes, and vice-versa. What I would be looking for would be the opposite of a dielectric. Would a negative permittivity material be an example of that?