How electricity, and generating electricity works on the atomic level?

I am trying to understand the basics physics as to how electricity works.

Unfortunately it seems most online material is either complex full blown mathematical equations, or water pump analogies.

I am interested in what happens at the single electron level. I guess i should start from what i think i understand.

Please correct me if any of my assumptions are wrong.

Energy Flow:

Different materials are made from molecules, those molecules are made from different atom types. Those atoms arrange themselves in in different configurations: ordered(called crystalline), random(amorphous), and a combination of both (Poly-crystalline).

The crystal is defined by a lattice and a basis. The lattice is a mathematical representation of points in space, and the basis is a "pattern" that gets pasted on each lattice point. The "pattern" is 1 or more atoms. The crystals are bound together by different types of bonds (ionic, covalent).

Since the lattice is just a representation, there is no meaning to start / end point, making the lattice have translational symmetry. Auguste Bravais discovered there are only 14 ways you can rearrange the lattice and keep translational symmetry.

Naturally crystals are formed when liquid cools down, since it happens in many locations and at different orientations, mostly poly-crystalline are formed. There are several crystal growth methods to create own more perfect crystals.

Each atom has an electron configuration, and has several different shells / levels of energy. There can be 2n^2 electrons per level. The lower the level the higher energy needed to bump the electron to the next level (because is closer to nucleus - where the protons are).

When arranging several atoms together, due to pauli exclusion principle (convoluted quantum mechanical principle that states two fermions(electrons) can not have the same quantum state) the atoms can not have the electrons at exactly the same energy level, forcing them to change slightly, split and spread into energy bands.

Conductivity determined by number of free electrons in the conductor that are free to move around. (more later)

The highest energy band available for material is called valence band. The next band is called conduction band. The conductivity is affected by the number occupied of electrons in valence band and the band gap between the valence to the conduction band. (more now)

If the valance band is half filled, there is room for the electrons to move resulting in high conductivity (metals). If the band is full, but the band gap to the conduction band is small enough so electrons can be excited to the next band where they can move and there is conductivity(semi conductors).

In insulators the valance band is full and the gap is too big, and an electron cant carry enough thermal energy to bump other electron through this gap.

Thus, the lattice, crystal structure and atom properties affect the band distribution which affect the number of free electrons.

When applying electric field on a wire, a force is applied to all the electrons, making them accelerate. Mean free path and mean free time represent the length & time on average before a collision happens with other atom / electron / material impurities etc. All of those collision, stopping and pushing, contribute to the net directional drift velocity of the electron as it moves in the conductor.

drift velocity = current.

voltage drop = energy used for exciting electrons over the gap.

When connecting current, to a circuit, due to the voltage (potential) difference at the start to the end, electrons start to flow. If there is no resistance, enormous current (as per ohm's law) flows, resulting in short circuit which burns(?)

For the circuit not to short, you must add resistance. By adding infinite resistance (say by cutting the wire so the medium is now air between the two) it is called open-circuit.

Also when using resistor need to take into account power dissipation using the power law. Most(?) resistors are only rated for 0.25 watt dissipation .

How is electricity generated?

Spinning a magnet with some properties of strength, physical size etc, which are summed up as magnetic flux (X), around / between a coil (Y) with some properties of length, resistance, number of turns. Using Faraday's law of electromagnetic induction you can calculate the voltage generated in the coil. The bigger the flux, the faster you spin it, the more coil, all result in higher voltage. (lets assume eventually DC current is produced)

Q: How long does this voltage last? Is because the more current drawn at this voltage, the magnetic reluctance is increased inside the coil due to electrons movement making in harder to spin the magnet? How is chemical battery affected?

Sources:

britneyspears.ac

MIT 802 (non atomic theory + equations)

MIT 2.57 (atomic / quantum equations mostly, some theory).

en.wikipedia.org/wiki/Classical_and_quantum_conductivity

These are all good questions! Based on your description I assume you haven't had an introduction to solid state physics yet? Let's take your image of an electron that "jumps" from atom to atom. In my understanding I wouln't describe it that way, to me it's a wavefunction of the electron that is almost independent from the valence electrons and you can use the free electron gas approximation. Why is this band independent? See the following picture for an intuitive understanding how the atomic potentials define the possible energy levels within a periodic arrangement of atoms: I think most of your questions will be easier to answer if you make yourself familiar with basic concepts and approximations people use to describe electrons in a solid first. Sure, a lot of things can be understood if we consider electrons to be little spheres that scatter from bigger spheres (ions), but you said you want to understand on the atomic level -> it's good to see the electron as a wave and see how this wave behaves in a lattice with certain boundary conditions.

First, I would read about a crystal. Atoms are arranged in a periodic lattice (assume a nice crystal for a first simple picture) and you can make assumptions based on this periodicity. You can define a unit cell and the Brillouin zone. You will see that the energy levels will sometimes split up in different bands and based on the filling of these bands you end up wih a metal, insulator etc. Electrons are fermions, can two electrons be in the same state? This defines the Fermi velocity.

This filling of the available energy levels describes the Fermi surface, a very useful tool to describe other more advanced concepts. Then you will see what happens if you change the arrangements of the atoms or why in different spatial directions electrons can move due to the bonding of different atomic orbitals.

This could be a good start ; ) -> http://britneyspears.ac/lasers.htm

There are other introductions out there, most of them describe the basics really well.

• As a beginner I was always frustrated with how the conduction band was explained by the numerous energy levels that can be occupied. It's probably done because it is link to the other orbitals. But the orbits in the conduction band span multiple atoms. We have no basis to suppose they are local to either an atom or a group of atoms (as I understand). So these lines in the conduction band never existed. If they're just explained as a gas it makes sense. There is a "quantum pressure" just like in neutron stars, and this explains the concept of "filling" the energy well. – Alan Rominger Apr 20 '13 at 20:53
• Hello AlanSE, why do you say these lines never existed? If you agree that let's say a hydrogen atom has sharp energy levels due to the Bohr-Sommerfeld quantization, then if you put two hydrogen atoms close to each other their wavefunctions will overlap and you end up with new sharp energy levels that define the new system (i.e. energy levels of a molecule). The same is even more amazing for $10^{23}$ of these atoms in a crystal and you will get bands in the continuum limit instead of single energy levels. E.g. quantum dots in a laser have these sharp energy levels due to confinement. – Mike Apr 20 '13 at 21:10
• I agree that if you had a metal composed of a few atoms then the conduction band energy states would be countable. Certainly. That would just apply for a microscopic dot of metal. – Alan Rominger Apr 20 '13 at 23:17
• @AlanSE The conduction band states are always countable in principle, just not in practice. The idea of a continuum of states inside a solid is just an approximation. – Mark Mitchison Apr 21 '13 at 13:40
• But are they really countable in principle? That's what I have trouble with. Electrons move in the conduction band. So maybe an electron's wave function spreads over a group of 10,000 atoms out of 1 kg of metal. In a short time, it's probably "orbiting" around an entirely new group of atoms. Or are all electrons spanning the entire 1 kg of metal? That can't be right. When I connect two electrical wires, the electrons don't orbit back and fourth between these wires. When dealing with electricity we can assign a countable speed to electrons. – Alan Rominger Apr 21 '13 at 13:49

Here are some very interesting lecture notes that may help you to better understand electron flow. http://www.phy-astr.gsu.edu/cymbalyuk/Lecture16.pdf

And some more notes from the same lectures http://www.phy-astr.gsu.edu/cymbalyuk/lectures.htm

Electricity at the microscopic level is related to motion of electrons which obeys the quantum mechanical laws. Since, many possible electron transport processes exist it is very hard to answer your question shortly. At least, the answer will be dependent on the material we are considering. For example, the conductance of metals and semiconductors is related to different electron transport processes. However, definitions of the electrical current, voltage drop, etc. following from the classical physics remain unchanged in the quantum mechanics.