Strictly speaking a scale measures weight and a balance measures mass, but it is common, especially in non-technical English, to refer to a "scale" in either case.
Most probably your home device is actually a scale and is somehow measuring the force imparted by whatever you put on the platform due to your local gravity. The function to display the result in either kilograms (mass) or pounds (force) is typically just a software conversion that assumes that your local gravity is a standard value for Earth, which is to say $g$ given approximately as $9.8\ \mathrm{m/s^2}$ or $32\ \mathrm{ft/s^2}$, depending on which system of units you are using.
Since this is typically not just a conversion from mass to force but also between metric and Imperial units, you can think of having two steps. Starting in pounds first "convert" to mass (slugs) staying within Imperial using the value of $g$ and then convert from Imperial to metric.
If you take that scale to the Moon, you will still get the correct weight, but that weight will now be less than what you would have measured for the same object on Earth because the Moon's gravity is less. So far so good, because that is the correct answer. If you ask the scale to give you a reading in kilograms though, you're probably in trouble. Unless it has a function that lets you recalibrate or reprogram it, it will not know that you are on the Moon and will happily do the conversion assuming the Earth's gravity rather than the Moon's. Of course this depends on your scale and how sophisticated it is. But if you're just talking a standard, household bathroom scale that was never meant to go to the Moon, this is probably what you'll get.
Now if you really did have a proper balance - something measuring mass - the situation is the same on Earth but reversed on the Moon. On Earth you get consistent results as shown in kilograms or in pounds under the same assumption about the strength of gravity, just now converted the other direction. On the Moon, you now get the correct mass, but if you ask for the result in pounds it will be wrong. (Again unless you've got some unusual device that let's you reprogram it for being on the Moon or otherwise recalibrate the internal conversion function.)