How does a star ignite? I remember reading that X-Rays are generated by 'braking' electrons in a Coolidge tube.
Is it fundamentally a matter that the extreme gravity immediately before a star ignites is so strong that it affects the hydrogen atoms to the point the velocity of it's components must be let-off in the form of heat & light? 
How does a star ignite?
 A: The nuclear fusion that powers stars has little to nothing to do with electrons. In the cores of stars, temperatures are high enough that all the electrons are stripped from the nuclei, leaving a pure plasma.
As stars contract and condense out of interstellar dust, their gravitational potential energy is converted to heat faster than this heat can be radiated away. Once the temperature reaches roughly $10^7\ \mathrm{K}$, protons (hydrogen nuclei, stripped of their electrons) have a nonnegligible chance of sticking together when they colide, with one of them converting to a neutron along the way:
$$ {}^1H + {}^1H \to {}^2H + e^+ + \nu_e. $$
This is the first step of the PP chain, and it releases energy. There are more steps that ultimately turn four protons into a helium-4 nucleus. In more massive stars than the Sun, there are other ways (e.g. the CNO cycle) to catalyze this process with the help of carbon, nitrogen, and oxygen.
In any event, there is nothing extreme about the gravity. It just happened to pull matter from a huge distance close together. If you took infinitely spread apart particles totaling mass $M$ and formed a uniformly dense sphere of radius $R$, the gravitational potential energy released would be
$$ \frac{3GM^2}{5R}, $$
about half of which you expect to go into heating the material. Once hot, hydrogen naturally forms helium in exothermic processes.
Stellar reactions are self-regulating in the sense that if the rate of fusion increases, the additional luminosity would push the outer layers of the star, causing the star to expand and cool, thus reducing the reaction rate. Thus as long as there is hydrogen in the core, stars more or less burn at a steady rate once ignited.
A: I was going to put in a detailed answer but the comment above me explains it pretty well. Basically, when the sun gains enough mass (has to be A LOT of mass. Nuclear fusion is a pretty powerful process), the gravity smashes the protons together and fuses them to create Helium nuclei. The 'smashing them together' part releases an immense amount of energy. Which is where the heat and light come from. So the 'igniting' is basically just something gaining enough mass to fuse protons (and other subatomic particles) together. The sun doesn't just suddenly ignite, though. It is a gradual process of heating up and collecting matter that happens over millions of years.
