Consider a water molecule:
As one can prove, the group symmetry for this molecule is $C_{2v}$, with a character table like
I am asked to use the projector operator formalism in order to determine the eigenvector associated with the normal mode which transforms like the totally symmetric representation, $A_1$.
My attempt
As my professor thaught us, I started by writing a vector
$$| \phi \rangle = (\delta x_1,\delta y_1,\delta x_2,\delta y_2,\delta x_3,\delta y_3)$$
which represents the deviations from the equilibrium positons. Then, I wrote the matrices representing each element of the symmetry group. Then, using the projector formalism, I wrote
$$P| \phi \rangle = \frac{1}{4}\left(D(E)+D(C2)+D(\sigma_v)+D(\sigma'_v)\right) |\phi \rangle$$
which yielded
$$\frac{1}{2}(\delta x_1, 2\delta y_1, \delta x_2, \delta y_3+\delta y_2, \delta x_3, \delta y_3 + \delta y_2)$$
My problems
- I can't understand why we choose the vector $| \phi \rangle$;
- What does the eigenvector we are looking for represent?
- Is there a different/other intuitive method of solving this problem?
Edit 1: After checking the maths again and fixing the axis, I got
$$\frac{1}{2}(0, 2\delta x_2, \delta x_2-\delta x_3, \delta z_2+\delta z_3, \delta x_2-\delta x_3, \delta z_2 + \delta z_3)$$