Consider setting up two experiments $\alpha $ and $\beta$.
In experimental setup $\alpha$ we can prepare $n$ possible pure states $\{| \psi_1 \rangle, | \psi_2 \rangle, ... | \psi_n \rangle\}$ with associated probabilities $\{p_1,p_2,...p_n\}$.
In experimental setup $\beta$ we prepare $m$ non-interacting systems. Each system prepared in its corresponding lower energy states $\{| \phi_1 \rangle, | \phi_2 \rangle, ... | \phi_n \rangle\}$.
My question is how would one deduce the density matrix operators for the quantum states prepared in each experiment. Is it simply a matter of noting that one can denote the density operator as a sum of a set of projectors as follows: $\rho = \sum_j p_j |j\rangle \langle j|.$
So then I may kind of assume that the density matrix operator for states prepared in $\alpha $ will be $\rho_{\alpha} = \sum_j p_i |\psi_i\rangle \langle \psi_i|.$
But I am unsure if this is correct I am also unsure how to construct the equivalent for experiment $\beta$.