ANSWER - Parts I & II
$\texttt{C O N T E N T S}$
$\texttt{Abstract}$
$\boldsymbol\S\texttt{ A. Proper homogeneous Lorentz transformations : }\Lambda$
$\boldsymbol\S\texttt{ B. Lorentz boosts : }\mathrm L\left(\mathbf{v}\right)$
$\boldsymbol\S\texttt{ C. The decomposition : }\Lambda = \rm L\left(\mathbf{v}\right)\mathcal R $
$\boldsymbol\S\texttt{ D. The uniqueness of the decomposition:}\rm L\left(\mathbf{v}'\right)\mathcal R'\!=\!\rm L\left(\mathbf{v}\right)\mathcal R \implies \mathbf{v}'\!=\!\mathbf{v},\mathcal R'\!=\!\mathcal R$
$\boldsymbol\S\texttt{ E. Decomposition with Lorentz boost first : }\Lambda = \rm \mathcal Q\, L\left(\mathbf u \right)$
$\boldsymbol\S\texttt{ F. Figures for }\Lambda \texttt{ and decompositions }\rm L\left(\mathbf{v}\right)\mathcal R,\:\mathcal R\,L\left(\mathbf{u}\right) $
ANSWER - Part I
Abstract
It will be proved that a proper homogeneous Lorentz transformation ($\Lambda$) can be decomposed by one and only one way in a Lorentz boost ($\rm L$) with velocity $\mathbf v$ and a rotation in space ($\mathcal R$)
\begin{equation}
\Lambda = \rm L\,\mathcal R
\tag{a}\label{a}
\end{equation}
in this order.The components of the velocity $\mathbf v$ and the characteristics of the rotation $\mathcal R$ (matrix elements, axis and angle) will be given as expressions of the matrix elements of $\Lambda$.
$\boldsymbol\S$ A. Proper homogeneous Lorentz transformations
For completeness we note the most important properties of Lorentz transformations as found in many textbooks and the Web. So let a 4-vector in Minkowski space-time
\begin{equation}
\mathbf X =
\begin{bmatrix}
\vphantom{\dfrac{a}{b}}\\
\mathbf x\vphantom{\dfrac{a}{b}}\\
\vphantom{\dfrac{a}{b}}\\
c\,t\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=
\begin{bmatrix}
x_1\vphantom{\dfrac{a}{b}}\\
x_2\vphantom{\dfrac{a}{b}}\\
x_3\vphantom{\dfrac{a}{b}}\\
x_4\vphantom{\dfrac{a}{b}}
\end{bmatrix}\,, \qquad x_k \in \mathbb R
\tag{A-01}\label{A-01}
\end{equation}
with norm
\begin{equation}
\Vert\mathbf X\Vert^2=\left(c\,t\right)^2-\vert\mathbf x \vert^2=x^2_4-\left(x^2_1+x^2_2+x^2_3\right)
\tag{A-02}\label{A-02}
\end{equation}
An homogeneous Lorentz transformation
\begin{equation}
\mathbf X'=
\begin{bmatrix}
\vphantom{\dfrac{a}{b}}\\
\mathbf x'\vphantom{\dfrac{a}{b}}\\
\vphantom{\dfrac{a}{b}}\\
c\,t'\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=
\begin{bmatrix}
x'_1\vphantom{\dfrac{a}{b}}\\
x'_2\vphantom{\dfrac{a}{b}}\\
x'_3\vphantom{\dfrac{a}{b}}\\
x'_4\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=
\begin{bmatrix}
\Lambda_{11} & \Lambda_{12} & \Lambda_{13} & \Lambda_{14}\vphantom{\dfrac{a}{b}}\\
\Lambda_{21} & \Lambda_{22} & \Lambda_{23} & \Lambda_{24}\vphantom{\dfrac{a}{b}}\\
\Lambda_{31} & \Lambda_{32} & \Lambda_{33} & \Lambda_{34}\vphantom{\dfrac{a}{b}}\\
\Lambda_{41} & \Lambda_{42} & \Lambda_{43} & \Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
x_1\vphantom{\dfrac{a}{b}}\\
x_2\vphantom{\dfrac{a}{b}}\\
x_3\vphantom{\dfrac{a}{b}}\\
x_4\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=\Lambda\mathbf X\,, \quad \Lambda_{ij} \in \mathbb R
\tag{A-03}\label{A-03}
\end{equation}
is one by which the norm \eqref{A-02} remains invariant. This norm is expressed in a different way as
\begin{align}
\Vert\mathbf{X}\Vert^2 &=-
\begin{bmatrix}
x_1 & x_2 & x_3 & x_4
\end{bmatrix}
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
x_1\vphantom{\dfrac{a}{b}}\\
x_2\vphantom{\dfrac{a}{b}}\\
x_3\vphantom{\dfrac{a}{b}}\\
x_4\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\nonumber\\
& =-
\begin{bmatrix}
x_1\vphantom{\dfrac{a}{b}}\\
x_2\vphantom{\dfrac{a}{b}}\\
x_3\vphantom{\dfrac{a}{b}}\\
x_4\vphantom{\dfrac{a}{b}}
\end{bmatrix}^{\boldsymbol{\top}}
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
x_1\vphantom{\dfrac{a}{b}}\\
x_2\vphantom{\dfrac{a}{b}}\\
x_3\vphantom{\dfrac{a}{b}}\\
x_4\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{A-04}\label{A-04}
\end{align}
that is
\begin{equation}
\Vert\mathbf X\Vert^2=-\mathbf X^{\boldsymbol{\top}} \eta\,\mathbf X
\tag{A-05}\label{A-05}
\end{equation}
where
\begin{equation}
\eta=
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{A-06}\label{A-06}
\end{equation}
From the invariant space-time interval
\begin{align}
&\Vert\mathbf X'\Vert^2=\Vert\mathbf X\Vert^2\:\Longrightarrow\:-\mathbf X'^{\boldsymbol{\top}} \eta\,\mathbf X'=-\mathbf X^{\boldsymbol{\top}} \eta\,\mathbf X\:\Longrightarrow
\nonumber\\
& \left(\Lambda\mathbf X\right)^{\boldsymbol{\top}} \eta\,\left(\Lambda\mathbf X\right)=\mathbf X^{\boldsymbol{\top}} \eta\,\mathbf X\:\Longrightarrow\:\mathbf X^{\boldsymbol{\top}}\Lambda^{\boldsymbol{\top}}\eta\,\Lambda\mathbf X=\mathbf X^{\boldsymbol{\top}} \eta\,\mathbf X
\nonumber
\end{align}
so for any $\mathbf X $
\begin{equation}
\mathbf X^{\boldsymbol{\top}}\left(\Lambda^{\boldsymbol{\top}}\eta\,\Lambda-\eta\right)\mathbf X=0
\nonumber
\end{equation}
hence
\begin{equation}
\boxed{\:\:\Lambda^{\boldsymbol{\top}}\eta\,\Lambda =\eta\vphantom{\dfrac{a}{b}}\:\:}
\tag{A-07}\label{A-07}
\end{equation}
written explicitly
\begin{equation}
\begin{bmatrix}
\Lambda_{11} & \Lambda_{21} & \Lambda_{31} & \Lambda_{41}\vphantom{\dfrac{a}{b}}\\
\Lambda_{12} & \Lambda_{22} & \Lambda_{32} & \Lambda_{42}\vphantom{\dfrac{a}{b}}\\
\Lambda_{13} & \Lambda_{23} & \Lambda_{33} & \Lambda_{43}\vphantom{\dfrac{a}{b}}\\
\Lambda_{14} & \Lambda_{24} & \Lambda_{34} & \Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
\Lambda_{11} & \Lambda_{12} & \Lambda_{13} & \Lambda_{14}\vphantom{\dfrac{a}{b}}\\
\Lambda_{21} & \Lambda_{22} & \Lambda_{23} & \Lambda_{24}\vphantom{\dfrac{a}{b}}\\
\Lambda_{31} & \Lambda_{32} & \Lambda_{33} & \Lambda_{34}\vphantom{\dfrac{a}{b}}\\
\Lambda_{41} & \Lambda_{42} & \Lambda_{43} & \Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{A-08}\label{A-08}
\end{equation}
or
\begin{equation}
\begin{bmatrix}
\Lambda_{11} & \Lambda_{21} & \Lambda_{31} & -\Lambda_{41}\vphantom{\dfrac{a}{b}}\\
\Lambda_{12} & \Lambda_{22} & \Lambda_{32} & -\Lambda_{42}\vphantom{\dfrac{a}{b}}\\
\Lambda_{13} & \Lambda_{23} & \Lambda_{33} & -\Lambda_{43}\vphantom{\dfrac{a}{b}}\\
\Lambda_{14} & \Lambda_{24} & \Lambda_{34} & -\Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
\Lambda_{11} & \Lambda_{12} & \Lambda_{13} & \Lambda_{14}\vphantom{\dfrac{a}{b}}\\
\Lambda_{21} & \Lambda_{22} & \Lambda_{23} & \Lambda_{24}\vphantom{\dfrac{a}{b}}\\
\Lambda_{31} & \Lambda_{32} & \Lambda_{33} & \Lambda_{34}\vphantom{\dfrac{a}{b}}\\
\Lambda_{41} & \Lambda_{42} & \Lambda_{43} & \Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{A-09}\label{A-09}
\end{equation}
Hence the first three column 4-vectors of $\Lambda$ are space-like with norm squared $+1$ while the fourth column 4-vector is time-like with norm squared $-1$ as in the following 4 equations
\begin{align}
\texttt{column 1 vector : }\Lambda^2_{11}+\Lambda^2_{21} +\Lambda^2_{31}-\Lambda_{41}^2 & =+1
\tag{A-10.1}\label{A-10.1}\\
\texttt{column 2 vector : }\Lambda^2_{12}+\Lambda^2_{22} +\Lambda^2_{32}-\Lambda_{42}^2 & =+1
\tag{A-10.2}\label{A-10.2}\\
\texttt{column 3 vector : }\Lambda^2_{13}+\Lambda^2_{23} +\Lambda^2_{33}-\Lambda_{43}^2 & =+1
\tag{A-10.3}\label{A-10.3}\\
\texttt{column 4 vector : }\Lambda^2_{14}+\Lambda^2_{24} +\Lambda^2_{34}-\Lambda_{44}^2 & =-1
\tag{A-10.4}\label{A-10.4}
\end{align}
Also the four column 4-vectors are mutually pseudo-orthogonal to each other. These properties are expressed through the following 6 equations
\begin{align}
\texttt{column 1 by column 2 : }\Lambda_{11}\Lambda_{12}+\Lambda_{21}\Lambda_{22} +\Lambda_{31}\Lambda_{32}-\Lambda_{41}\Lambda_{42} & =0
\tag{A-10.5}\label{A-10.5}\\
\texttt{column 1 by column 3 : }\Lambda_{11}\Lambda_{13}+\Lambda_{21}\Lambda_{23} +\Lambda_{31}\Lambda_{33}-\Lambda_{41}\Lambda_{43} & =0
\tag{A-10.6}\label{A-10.6}\\
\texttt{column 1 by column 4 : }\Lambda_{11}\Lambda_{14}+\Lambda_{21}\Lambda_{24} +\Lambda_{31}\Lambda_{34}-\Lambda_{41}\Lambda_{44} & =0
\tag{A-10.7}\label{A-10.7}\\
\texttt{column 2 by column 3 : }\Lambda_{12}\Lambda_{13}+\Lambda_{22}\Lambda_{23} +\Lambda_{32}\Lambda_{33}-\Lambda_{42}\Lambda_{43} & =0
\tag{A-10.8}\label{A-10.8}\\
\texttt{column 2 by column 4 : }\Lambda_{12}\Lambda_{14}+\Lambda_{22}\Lambda_{24} +\Lambda_{32}\Lambda_{34}-\Lambda_{42}\Lambda_{44} & =0
\tag{A-10.9}\label{A-10.9}\\
\texttt{column 3 by column 4 : }\Lambda_{13}\Lambda_{14}+\Lambda_{23}\Lambda_{24} +\Lambda_{33}\Lambda_{34}-\Lambda_{43}\Lambda_{44} & =0
\tag{A-10.10}\label{A-10.10}
\end{align}
The 16 elements of $\Lambda$ must satisfy the 10 equations \eqref{A-10.1}-\eqref{A-10.10}. Hence, irrelevant here, the set of all transformations $\Lambda$ with property \eqref{A-07} must be 6-parametric.
From equation \eqref{A-07}
\begin{equation}
\det\left(\Lambda^{\boldsymbol{\top}}\eta\,\Lambda\right) =\det\eta \quad \Longrightarrow \quad \det\Lambda^{\boldsymbol{\top}}\cdot\det\eta\cdot\det\Lambda=\det\eta\quad \Longrightarrow
\nonumber
\end{equation}
\begin{equation}
\left(\det\Lambda\right)^2=+1 \quad \texttt{or} \quad \det\Lambda=\pm 1
\tag{A-11}\label{A-11}
\end{equation}
Now, the element $\Lambda_{44}$ is the factor relating the time variables $t,t'$
\begin{equation}
t'=\Lambda_{44}\,t \cdots
\tag{A-12}\label{A-12}
\end{equation}
To exclude the case of time inversion it's necessary this factor to be positive. But from \eqref{A-10.4}
\begin{equation}
\Lambda_{44}^2=1+\left(\Lambda^2_{14}+\Lambda^2_{24}+\Lambda^2_{34}\right)\ge +1
\tag{A-13}\label{A-13}
\end{equation}
So we must have
\begin{equation}
\boxed{\:\:\Lambda_{44} \ge +1 \qquad \texttt{(orthochronus)}\vphantom{\dfrac{a}{b}}\:\:}
\tag{A-14}\label{A-14}
\end{equation}
On the other hand to exclude space inversion we must have from \eqref{A-11}
\begin{equation}
\boxed{\:\:\det\Lambda=+1\qquad \texttt{(space inversion exclusion)}\vphantom{\dfrac{a}{b}}\:\:}
\tag{A-15}\label{A-15}
\end{equation}
An homogeneous Lorentz transformation that beyond condition \eqref{A-07} satisfies also the orthochronus condition \eqref{A-14} and the excluding space inversion condition \eqref{A-15} is called proper homogeneous Lorentz transformation.
Note also that applying $\eta$ on the two sides of \eqref{A-07} we have
\begin{equation}
\eta\,\Lambda^{\boldsymbol{\top}}\eta\,\Lambda =\eta^2=\mathrm I\quad \Longrightarrow \quad \left(\eta\,\Lambda^{\boldsymbol{\top}}\eta\right)\Lambda =\mathrm I
\nonumber
\end{equation}
so
\begin{equation}
\Lambda^{-1} =\eta\,\Lambda^{\boldsymbol{\top}}\eta
\tag{A-16}\label{A-16}
\end{equation}
explicitly
\begin{equation}
\Lambda^{-1} =
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
\Lambda_{11} & \Lambda_{21} & \Lambda_{31} & \Lambda_{41}\vphantom{\dfrac{a}{b}}\\
\Lambda_{12} & \Lambda_{22} & \Lambda_{32} & \Lambda_{42}\vphantom{\dfrac{a}{b}}\\
\Lambda_{13} & \Lambda_{23} & \Lambda_{33} & \Lambda_{43}\vphantom{\dfrac{a}{b}}\\
\Lambda_{14} & \Lambda_{24} & \Lambda_{34} & \Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
+1 & \hphantom{+}0& \hphantom{+}0& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & +1 & \hphantom{+}0 & \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 & \hphantom{+}0 & +1& \hphantom{-}0\vphantom{\dfrac{a}{b}}\\
\hphantom{+}0 &\hphantom{+}0 &\hphantom{+}0 &-1\vphantom{\dfrac{a}{b}}
\end{bmatrix}\quad \Longrightarrow
\nonumber
\end{equation}
\begin{equation}
\Lambda^{-1} =
\begin{bmatrix}
\hphantom{-}\Lambda_{11} & \hphantom{-}\Lambda_{21} & \hphantom{-}\Lambda_{31} & -\Lambda_{41}\vphantom{\dfrac{a}{b}}\\
\hphantom{-}\Lambda_{12} & \hphantom{-}\Lambda_{22} & \hphantom{-}\Lambda_{32} & -\Lambda_{42}\vphantom{\dfrac{a}{b}}\\
\hphantom{-}\Lambda_{13} & \hphantom{-}\Lambda_{23} & \hphantom{-}\Lambda_{33} & -\Lambda_{43}\vphantom{\dfrac{a}{b}}\\
-\Lambda_{14} & -\Lambda_{24} & -\Lambda_{34} & \hphantom{-}\Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{A-17}\label{A-17}
\end{equation}
Note that $\Lambda^{-1}$ is also a proper homogeneous Lorentz transformation since

$\boldsymbol\S$ B. Lorentz boosts
A Lorentz boost with velocity $\mathbf v$
\begin{equation}
\mathbf v =
\begin{bmatrix}
v_1 \vphantom{\dfrac{a}{b}}\\
v_2 \vphantom{\dfrac{a}{b}}\\
v_3 \vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{B-01}\label{B-01}
\end{equation}
has in general the following form
\begin{equation}
\mathrm L\left(\mathbf{v}\right) =
\begin{bmatrix}
\mathrm I+\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \mathbf v ^{\boldsymbol{\top}} & -\dfrac{\gamma_v}{c}\mathbf v \vphantom{\dfrac{\gamma}{c}\boldsymbol{\upsilon}^{\boldsymbol{\top}}}\vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}\\
-\dfrac{\gamma_v}{c}\mathbf v^{\boldsymbol{\top}} & \hphantom{-}\gamma_v \vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}
\end{bmatrix}
\tag{B-02}\label{B-02}
\end{equation}
where
\begin{equation}
\gamma_v=\left(1-\dfrac{v^2}{c^2}\right)^{-\frac12}
\tag{B-03}\label{B-03}
\end{equation}
Note that
\begin{equation}
\mathbf v \mathbf v ^{\boldsymbol{\top}}=
\begin{bmatrix}
v_1 \vphantom{\dfrac{a}{b}}\\
v_2 \vphantom{\dfrac{a}{b}}\\
v_3 \vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
v_1 \vphantom{\dfrac{a}{b}}\\
v_2 \vphantom{\dfrac{a}{b}}\\
v_3 \vphantom{\dfrac{a}{b}}
\end{bmatrix} ^{\boldsymbol{\top}}
=
\begin{bmatrix}
v_1 \vphantom{\dfrac{a}{b}}\\
v_2 \vphantom{\dfrac{a}{b}}\\
v_3 \vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
v_1 & v_2 & v_3\vphantom{\dfrac{a}{b}}
\end{bmatrix}
=
\begin{bmatrix}
v^2_1 & v_1v_2 & v_1v_3 \vphantom{\dfrac{a}{b}}\\
v_2v_1 & v^2_2 & v_2v_3 \vphantom{\dfrac{a}{b}}\\
v_3v_1 & v_3v_2 & v^2_3\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{B-04}\label{B-04}
\end{equation}
A Lorentz boost is a special kind of proper homogeneous Lorentz transformation with two additional properties : it is symmetric with inverse
\begin{equation}
\mathrm L^{-1}=\bigl[\mathrm L\left(\mathbf{v}\right)\bigr]^{-1} =\mathrm L\left(-\mathbf{v}\right) =
\begin{bmatrix}
\mathrm I+\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \mathbf v ^{\boldsymbol{\top}} & +\dfrac{\gamma_v}{c}\mathbf v \vphantom{\dfrac{\gamma}{c}\boldsymbol{\upsilon}^{\boldsymbol{\top}}}\vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}\\
+\dfrac{\gamma_v}{c}\mathbf v^{\boldsymbol{\top}} & \hphantom{-}\gamma_v \vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}
\end{bmatrix}
\tag{B-05}\label{B-05}
\end{equation}
$\boldsymbol\S$ C. The decomposition
The question is if a proper homogeneous Lorentz transformation
\begin{equation}
\Lambda =
\begin{bmatrix}
\Lambda_{11} & \Lambda_{12} & \Lambda_{13} & \Lambda_{14}\vphantom{\dfrac{a}{b}}\\
\Lambda_{21} & \Lambda_{22} & \Lambda_{23} & \Lambda_{24}\vphantom{\dfrac{a}{b}}\\
\Lambda_{31} & \Lambda_{32} & \Lambda_{33} & \Lambda_{34}\vphantom{\dfrac{a}{b}}\\
\Lambda_{41} & \Lambda_{42} & \Lambda_{43} & \Lambda_{44}\vphantom{\dfrac{a}{b}}
\end{bmatrix}\quad \Lambda^{\boldsymbol{\top}}\eta\,\Lambda =\eta\,,\quad \Lambda_{44}\ge +1\,,\quad \det\Lambda=+1
\tag{C-01}\label{C-01}
\end{equation}
could be decomposed in a space transformation $\mathcal R$ followed by a Lorentz boost $\rm L$ with velocity $\mathbf v$
\begin{equation}
\Lambda = \rm L\left(\mathbf{v}\right)\mathcal R
\tag{C-02}\label{C-02}
\end{equation}
Consider that the space transformation $\mathcal R$ is represented by the following $4\times 4-$matrix
\begin{equation}
\mathcal R=
\begin{bmatrix}
\hphantom{=}\rm R\hphantom{^{\boldsymbol{\top}}} & \hphantom{====}\boldsymbol 0\hphantom{=} \vphantom{\dfrac{\gamma}{c}\boldsymbol{\upsilon}^{\boldsymbol{\top}}}\vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}\\
\hphantom{=}\boldsymbol 0^{\boldsymbol{\top}} & \hphantom{====}1\hphantom{=} \vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}
\end{bmatrix}
\tag{C-03}\label{C-03}
\end{equation}
where
\begin{equation}
\mathrm R =
\begin{bmatrix}
R_{11} & R_{12} & R_{13} \vphantom{\dfrac{a}{b}}\\
R_{21} & R_{22} & R_{23}\vphantom{\dfrac{a}{b}}\\
R_{31} & R_{32} & R_{33}
\end{bmatrix}\qquad R_{ij} \in \mathbb R
\tag{C-04}\label{C-04}
\end{equation}
From equations \eqref{B-02},\eqref{C-03} we have
\begin{align}
\rm L\left(\mathbf{v}\right)\mathcal R & =
\begin{bmatrix}
\mathrm I+\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \mathbf v ^{\boldsymbol{\top}} & -\dfrac{\gamma_v}{c}\mathbf v \vphantom{\dfrac{\gamma}{c}\boldsymbol{\upsilon}^{\boldsymbol{\top}}}\vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}\\
-\dfrac{\gamma_v}{c}\mathbf v^{\boldsymbol{\top}} & \hphantom{-}\gamma_v \vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}
\end{bmatrix}
\begin{bmatrix}
\hphantom{=}\rm R\hphantom{^{\boldsymbol{\top}}} & \hphantom{====}\boldsymbol 0\hphantom{=} \vphantom{\dfrac{\gamma}{c}\boldsymbol{\upsilon}^{\boldsymbol{\top}}}\vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}\\
\hphantom{=}\boldsymbol 0^{\boldsymbol{\top}} & \hphantom{====}1\hphantom{=} \vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}
\end{bmatrix}\quad \Longrightarrow
\nonumber\\
\rm L\left(\mathbf{v}\right)\mathcal R & =
\begin{bmatrix}
\mathrm R+\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \left(\mathrm R^{\boldsymbol{\top}}\mathbf v\right)^{\boldsymbol{\top}} & -\dfrac{\gamma_v}{c}\mathbf v \vphantom{\dfrac{\gamma}{c}\boldsymbol{\upsilon}^{\boldsymbol{\top}}}\vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}\\
-\dfrac{\gamma_v}{c}\left(\mathrm R^{\boldsymbol{\top}}\mathbf v\right)^{\boldsymbol{\top}} & \hphantom{-}\gamma_v \vphantom{\dfrac{\dfrac{a}{b}}{\dfrac{a}{b}}}
\end{bmatrix}
\tag{C-05}\label{C-05}
\end{align}
For decomposition \eqref{C-02} to be valid the following equality must be satisfied if we insert expressions \eqref{C-01},\eqref{C-05} for $\Lambda$ and $\rm L\left(\mathbf{v}\right)\mathcal R$ respectively
\begin{equation}
\underbrace{
\begin{bmatrix}
\begin{array}{ccc|c}
\Lambda_{11} & \Lambda_{12} & \Lambda_{13} & \Lambda_{14}\vphantom{\dfrac{a}{b}}\\
\Lambda_{21} & \Lambda_{22} & \Lambda_{23} & \Lambda_{24}\vphantom{\dfrac{a}{b}}\\
\Lambda_{31} & \Lambda_{32} & \Lambda_{33} & \Lambda_{34}\vphantom{\dfrac{a}{\tfrac{a}{b}}}\\
\hline
\Lambda_{41} & \Lambda_{42} & \Lambda_{43} & \Lambda_{44}\vphantom{\dfrac{\tfrac{a}{b}}{b}}
\end{array}
\end{bmatrix}}_{\Lambda}
=
\underbrace{
\begin{bmatrix}
\begin{array}{ccc|c}
& & & \vphantom{\dfrac{a}{b}}\\
& \mathrm R+\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \left(\mathrm R^{\boldsymbol{\top}}\mathbf v\right)^{\boldsymbol{\top}} & & -\dfrac{\gamma_v}{c}\mathbf v\vphantom{\dfrac{a}{b}}\\
& & & \vphantom{\dfrac{a}{b}}\\
\hline
& -\dfrac{\gamma_v}{c}\left(\mathrm R^{\boldsymbol{\top}}\mathbf v\right)^{\boldsymbol{\top}} & & \gamma_v \vphantom{\dfrac{\tfrac{a}{b}}{b}}
\end{array}
\end{bmatrix}}_{\rm L\left(\mathbf{v}\right)\mathcal R}
\tag{C-06}\label{C-06}
\end{equation}
Equating the fourth column of the matrix in the left to the fourth column of the matrix in the right we determine the boost velocity $\mathbf v$ and the $\gamma-$factor in terms of the elements $\Lambda_{ij}$
\begin{equation}
\begin{bmatrix}
\begin{array}{c}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{\tfrac{a}{b}}}\\
\hline
\Lambda_{44}\vphantom{\dfrac{\tfrac{a}{b}}{b}}
\end{array}
\end{bmatrix}
=
\begin{bmatrix}
\begin{array}{c}
\vphantom{\dfrac{a}{b}}\\
-\dfrac{\gamma_v}{c}\mathbf v \vphantom{\dfrac{a}{b}}\\
\vphantom{\dfrac{a}{\tfrac{a}{b}}}\\
\hline
\gamma_v\vphantom{\dfrac{\tfrac{a}{b}}{b}}
\end{array}
\end{bmatrix}\qquad \Longrightarrow
\nonumber
\end{equation}
\begin{equation}
\mathbf v=\begin{bmatrix}
v_1 \vphantom{\dfrac{a}{b}}\\
v_2 \vphantom{\dfrac{a}{b}}\\
v_3 \vphantom{\dfrac{a}{b}}
\end{bmatrix}=-\dfrac{c}{\Lambda_{44}}
\begin{bmatrix}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{b}}
\end{bmatrix}\quad \texttt{and} \quad \gamma_v = \Lambda_{44}
\tag{C-07}\label{C-07}
\end{equation}
Equation \eqref{C-07} is a great advantage because we can express the Lorentz boost $\rm L\left(\mathbf{v}\right)$ and its inverse $\mathrm L^{-1}=\bigl[\mathrm L\left(\mathbf{v}\right)\bigr]^{-1} =\mathrm L\left(-\mathbf{v}\right)$ in terms of the elements $\Lambda_{ij}$. Since from \eqref{C-02}
\begin{equation}
\mathcal R=\bigl[\mathrm L\left(\mathbf{v}\right)\bigr]^{-1}\Lambda=\mathrm L\left(-\mathbf{v}\right)\Lambda
\tag{C-08}\label{C-08}
\end{equation}
above equation has in the lhs the unknown matrix $\mathcal R$ while the rhs is an expression in terms of the elements $\Lambda_{ij}$. So from above equation \eqref{C-08} we could determine completely the matrix $\mathcal R$ what we will do in the following.
To express the inverse of the Lorentz boost \eqref{B-05} in terms of the elements $\Lambda_{ij}$ we have, based on equation \eqref{C-07}
\begin{align}
\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \mathbf v ^{\boldsymbol{\top}} & =\dfrac{\Lambda^2_{44}}{c^2 \left(\Lambda_{44}+1\right)}
\left(-\dfrac{c}{\Lambda_{44}}
\begin{bmatrix}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{b}}
\end{bmatrix}\right)
\left(-\dfrac{c}{\Lambda_{44}}
\begin{bmatrix}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{b}}
\end{bmatrix}\right) ^{\boldsymbol{\top}}
\nonumber\\
& =\dfrac{1}{\Lambda_{44}+1}
\begin{bmatrix}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{b}}
\end{bmatrix} ^{\boldsymbol{\top}}=
\dfrac{1}{\Lambda_{44}+1}
\begin{bmatrix}
\Lambda_{14} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34} \vphantom{\dfrac{a}{b}}
\end{bmatrix}
\begin{bmatrix}
\Lambda_{14} & \Lambda_{24} & \Lambda_{34}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\: \Longrightarrow
\nonumber
\end{align}
\begin{equation}
\dfrac{\gamma^2_v}{c^2 \left(\gamma_v+1\right)}\mathbf v \mathbf v ^{\boldsymbol{\top}} = \dfrac{1}{\Lambda_{44}+1}
\begin{bmatrix}
\Lambda^2_{14} & \Lambda_{14}\Lambda_{24} & \Lambda_{14}\Lambda_{34} \vphantom{\dfrac{a}{b}}\\
\Lambda_{24}\Lambda_{14} & \Lambda^2_{24} & \Lambda_{24}\Lambda_{34} \vphantom{\dfrac{a}{b}}\\
\Lambda_{34}\Lambda_{14} & \Lambda_{34}\Lambda_{24} & \Lambda^2_{34}\vphantom{\dfrac{a}{b}}
\end{bmatrix}
\tag{C-09}\label{C-09}
\end{equation}
Hence from \eqref{B-05}
\begin{equation}
\mathrm L\left(-\mathbf{v}\right)=
\begin{bmatrix}
1+\dfrac{\Lambda^2_{14}}{\Lambda_{44}+1} & \dfrac{\Lambda_{14}\Lambda_{24}}{\Lambda_{44}+1} & \dfrac{\Lambda_{14}\Lambda_{34}}{\Lambda_{44}+1} & - \Lambda_{14}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\dfrac{\Lambda_{24}\Lambda_{14}}{\Lambda_{44}+1} & 1+\dfrac{\Lambda^2_{24}}{\Lambda_{44}+1} & \dfrac{\Lambda_{24}\Lambda_{34}}{\Lambda_{44}+1} & - \Lambda_{24}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\dfrac{\Lambda_{34}\Lambda_{14}}{\Lambda_{44}+1} & \dfrac{\Lambda_{34}\Lambda_{24}}{\Lambda_{44}+1} & 1+\dfrac{\Lambda^2_{34}}{\Lambda_{44}+1} & - \Lambda_{34}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
- \Lambda_{14} & - \Lambda_{24} & - \Lambda_{34} & \hphantom{-} \Lambda_{44}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}
\tag{C-10}\label{C-10}
\end{equation}
and equation \eqref{C-08} yields
\begin{align}
&\mathcal R =
\begin{bmatrix}
\:\: & & & \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\:\: & \mathrm R & & \boldsymbol 0 \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\:\: & & & \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\:\:\:\:\:\: & \:\:\boldsymbol 0 ^{\boldsymbol{\top}}\:\: & \:\:\:\: & \:\:\:1\:\:\: \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}=
\begin{bmatrix}
\:\:R_{11} & R_{12} & R_{13} & 0 \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\:\:R_{21} & R_{22} & R_{23} & 0 \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\:\:R_{31} & R_{32} & R_{33} & 0 \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\:\:\:\:0\:\: & \:\:0\:\: & \:\:0\:\: & \:\:\:1\:\:\: \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}=
\tag{C-11}\label{C-11}\\
&\begin{bmatrix}
1+\dfrac{\Lambda^2_{14}}{\Lambda_{44}+1} & \dfrac{\Lambda_{14}\Lambda_{24}}{\Lambda_{44}+1} & \dfrac{\Lambda_{14}\Lambda_{34}}{\Lambda_{44}+1} & - \Lambda_{14}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\dfrac{\Lambda_{24}\Lambda_{14}}{\Lambda_{44}+1} & 1+\dfrac{\Lambda^2_{24}}{\Lambda_{44}+1} & \dfrac{\Lambda_{24}\Lambda_{34}}{\Lambda_{44}+1} & - \Lambda_{24}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\dfrac{\Lambda_{34}\Lambda_{14}}{\Lambda_{44}+1} & \dfrac{\Lambda_{34}\Lambda_{24}}{\Lambda_{44}+1} & 1+\dfrac{\Lambda^2_{34}}{\Lambda_{44}+1} & - \Lambda_{34}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
- \Lambda_{14} & - \Lambda_{24} & - \Lambda_{34} & \hphantom{-} \Lambda_{44}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}
\begin{bmatrix}
\Lambda_{11} & \Lambda_{12} & \Lambda_{13} & \Lambda_{14}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\Lambda_{21} & \Lambda_{22} & \Lambda_{23} & \Lambda_{24}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\Lambda_{31} & \Lambda_{32} & \Lambda_{33} & \Lambda_{34}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\Lambda_{41} & \Lambda_{42} & \Lambda_{43} & \Lambda_{44}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}
\nonumber
\end{align}
Elaborating the matrix product of the rhs and using the properties \eqref{A-10.1}-\eqref{A-10.10} we have
\begin{equation}
\mathrm R=
\begin{bmatrix}
R_{11} & R_{12} & R_{13} \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
R_{21} & R_{22} & R_{23}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
R_{31} & R_{32} & R_{33} \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}=
\begin{bmatrix}
\Lambda_{11}-\dfrac{\Lambda_{14}\Lambda_{41}}{\Lambda_{44}+1} & \Lambda_{12}-\dfrac{\Lambda_{14}\Lambda_{42}}{\Lambda_{44}+1} & \Lambda_{13}-\dfrac{\Lambda_{14}\Lambda_{43}}{\Lambda_{44}+1} \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\Lambda_{21}-\dfrac{\Lambda_{24}\Lambda_{41}}{\Lambda_{44}+1} & \Lambda_{22}-\dfrac{\Lambda_{24}\Lambda_{42}}{\Lambda_{44}+1} & \Lambda_{23}-\dfrac{\Lambda_{24}\Lambda_{43}}{\Lambda_{44}+1} \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\\
\Lambda_{31}-\dfrac{\Lambda_{34}\Lambda_{41}}{\Lambda_{44}+1} & \Lambda_{32}-\dfrac{\Lambda_{34}\Lambda_{42}}{\Lambda_{44}+1} & \Lambda_{33}-\dfrac{\Lambda_{34}\Lambda_{43}}{\Lambda_{44}+1} \vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}
\end{bmatrix}
\tag{C-12}\label{C-12}
\end{equation}
or in an equation only
\begin{equation}
\boxed{\:\:R_{ij} =\Lambda_{ij}-\dfrac{\Lambda_{i4}\Lambda_{4j}}{\Lambda_{44}+1}\vphantom{\dfrac{\tfrac{a}{b}}{\tfrac{a}{b}}}\:\:}
\tag{C-13}\label{C-13}
\end{equation}
Proof that $\rm R$ represents a pure rotation and expressions for its axis and angle are given in ANSWER - Part II.
(to be continued in ANSWER - Part II)