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In my text book they stated:

As an example, the wave function of an electron that is in position $2p$ in a hydrogen atom given by: $$ \varPhi(r,\theta,\varphi)=\frac{1}{4\sqrt{2\pi}a_0^{3/2}}\frac{r}{a_0} e^\frac{-r}{2a_0}\cos\theta $$ If we want to calculate the average electrostatic force of the electron (Assume that the atomic nucleus is at rest) then we need to use the Coulomb's law: $$ \vec{F}=-\frac{kq_e^2}{r^2}\hat{r} $$

I don't understand why the Coulomb's law is between two electrons and not between the electron and proton inside the atomic nucleus. did they meant the proton but because $|q_e|=|q_p|$ then they just wrote $q_e$?

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    $\begingroup$ Yes, because the expression for the Coulomb force explicitly contains the minus sign $\endgroup$ Commented Oct 10, 2020 at 10:33

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$$q_e$$ just means elementary charge, not charge of an electron.

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  • $\begingroup$ What is the difference? $\endgroup$
    – vesii
    Commented Oct 10, 2020 at 11:38
  • $\begingroup$ the difference is that the coulomb force was calculated with the elementary charge , not the charge of an electron, so it is the law for an e around a charge qe, here the charge of the proton, $\endgroup$
    – trula
    Commented Oct 10, 2020 at 14:28
  • $\begingroup$ Actually, $q_e = -e$. $e$ is the electronic charge and is equal to the charge of a proton, and negative of the electron. $\endgroup$
    – Bill N
    Commented Oct 10, 2020 at 17:09
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It seems your textbook skipped a step in the explanation.

In a hydrogen atom the Coulomb force between proton ($p$) and electron ($e$) is $$\vec{F}=\frac{kq_pq_e}{r^2}\hat{r}$$

Now the proton charge is the opposite of the electron charge: $$q_p=-q_e$$

Therefore you can rewrite the Coulomb force between proton and electron as $$\vec{F}=-\frac{kq_e^2}{r^2}\hat{r}$$

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