As stated in almost all the answers, $\kappa>0$ does indeed define a set of transformation that preserves the Euclidean metric, with the Lorentz group $SO(1,3)$ being replaced by $SO(4)$. Although this does make mathematical sense, there's an internal physical inconsistency, which shows that an universe with $\kappa>0$ is not possible.
To show the inconsistency, first note that homogeneity and isotropy of space along with the principle of relativity not only gives us the spacetime transformations, but also gives us the velocity addition rule$^*$, which looks like $$w=\frac{u+v}{1-\kappa uv} .$$ Since $\kappa>0$, assume $\kappa=1/c^2,\ c\in\mathbb R,\ c<\infty$. Then $$w=\frac{u+v}{1- uv/c^2}.$$ We first show that there exists a velocity greater than $c$. To show this, consider $u=c/2=v$. Then $w=c/(3/4)=4c/3>c$.
Now, let $\gamma_u=1/\sqrt{1+\kappa v^2}=1/\sqrt{1+v^2/c^2}$. The spacetime transformation tells us that $\gamma_0=1$ and hence the square root in $\gamma_u$ is the positive square root and thus $\gamma_u>0\ \forall u\in \mathbb R$.
The assumed postulates also lets us derive$^*$ $$\gamma_w=\gamma_u\gamma_v(1-\kappa uv)=\gamma_u\gamma_v(1-uv/c^2).$$
Consider $u,v$ such that $uv>c^2$. This is possible because there exist velocities greater than $c$ as we have shown. Then $1-uv/c^2<0\Rightarrow \gamma_w=\gamma_u\gamma_v(1-uv/c^2)<0\Rightarrow \gamma_w<0$ which is a contradiction.
This is the internal inconsistency. The postulates do not allow for an universe with $\kappa>0$.
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$^*$ The derivation of these facts is very beautifully shown in this paper. It's simple and concise, and the proof of inconsistency is also in the paper.