Can ALL magnetic fields be accounted as some kind of electric field from a particular reference frame?
No. Relativity really tells us that electric and magnetic fields are on an equal footing. In some situations, you can find a frame where there's only an electric field. In others, you can find a frame where there's only a magnetic field. But most of the time, you can't do either.
And if there is relative motion between the electrons of the wire and the charge at rest(from the lab frame), then will it not experience a magnetic force from the electron's reference frame? I am not sure if that is the actual case, so even if the stationary charge is attracted to the wire, can it be accounted as an electrostatic force from the lab frame due to length contraction and as a magnetic force from the electrons POI?
I'm not sure if this is getting at your confusion, but recall some basic examples in relativity. For example, suppose that in your frame a spaceship passes by you. In your frame, this can happen really quickly because the spaceship is length contracted. In the spaceship's frame, it happens really quickly according to you because your time is dilated. So what's really going on? Is it really time dilation or is it really length contraction? Of course, the point is that the two frames are on an equal footing. Time dilation in one frame can be equivalently described as length contraction in another, and neither is inherently more correct.
Similarly, in some situations, what can be described as a magnetic force due to motion in a magnetic field in one frame, could be described as an electric force due to an electric field in another frame. In each individual frame, absolutely everything works as usual: Maxwell's equations are true, the Lorentz force expression holds, and so on. So, for example, in a frame where a charge is still, it experiences no magnetic force, even if it might in a different frame where it is moving. The description of what is going on changes between different frames, but neither frame is more "correct".
Saying that magnetic forces are "always really just because of electric forces due to a charge imbalance due to length contraction in a different frame" doesn't make sense. It doesn't work in general, and it's kind of like saying "time dilation doesn't really exist, only length contraction does". It's actually the exact opposite of the spirit of relativity.