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Fiber optics make use of total internal reflection for transmitting signals through them. Associated with fiber optics are many kinds of losses such as loss of signals due to light rays entering at angles more than the acceptance angle.

If in theory, we could make fibers that are "mirrored" on the inside which would reflect all rays of light regardless of their angle of incidence, would that improve the capacity of these fibers?

One possible reason why I think mirrored fibers should not be used is that rays entering at very high angles (approaching 90 degrees) will undergo a large number of reflections due to which they will arrive at the other end very late. This could cause interference with other data that has been sent.

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The thing is that there are no really good mirror coatings. From this plot from Edmund Optics, a reseller for technical optics, you can see that for 1-1.5 µm (telecommunication wavelength) the reflectance doesn't go higher than 98% (that's normal incidence, it will be a little higher for grazing incidence).

Reflectance Data

In contrast, the inner surface of a glass fiber with a clean surface has 100% reflectance. It's also important to note that the transmission within fused quartz fibers of 1-1.5 µm is particularly high, so there are very little transmission losses either, as can be seen in this plot (theoretical model) from RP Photonics:

Silica Fiber Transmission

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I think the main reason is practicality. In the normal process of manufacturing of optical fiber, the material is simply pulled out of the preform, and the core and the cladding result directly from this (having been formed in the preform before pulling). If a mirror surface were used instead of low-index cladding, you'd have to find a material that would:

  1. have near 100% reflectivity,
  2. be pullable at the temperatures of pulling of the glass from which the fiber is made,
  3. retain its reflectivity and smoothness after pulling,
  4. retain enough thickness to avoid becoming translucent.

The answer by zonksoft also explains that even for normal mirrors the metallic coatings are still far from being 100% reflective, unlike the total internal reflection at the core-cladding interface of the fibers. Add this to the above points, and you'll see that regular reflection is not really practical for optical signal transmission over long distances.

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