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I have always been confused about the antisymmetry of the wave function for fermions. Suppose we have a wave function such $\psi$ such that $$\psi(x_1,x_2)=-\psi(x_2,x_1)\tag{1}$$

Now suppose we have coordinate transformation $f_1,f_2$ such that we have

$$\psi(x_1,x_2)= \psi(f_1(y_1,y_1),f_2(y_1,y_2))=\phi(y_1,y_2)\tag{2}$$

How can we prove that

$$\phi(y_1,y_2)=-\phi(y_2,y_1)~?\tag{3}$$

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  • $\begingroup$ It's worth being careful about trying to physically interpret the mathematics too literally. The wave function is not a real thing, it is a mathematical object which we have to assign to something physical that we can measure. $\endgroup$
    – Charlie
    Commented Apr 24, 2020 at 0:09
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    $\begingroup$ is $x_1-x_2$ the same as $x_2-x_1$, even if the coordinates are imaginations of our mind? $\endgroup$ Commented Apr 24, 2020 at 1:07
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    $\begingroup$ Comment to the post (v4): Consider to double-check eq. (2) for typos. $\endgroup$
    – Qmechanic
    Commented Feb 23 at 7:04

2 Answers 2

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How can we prove that $\phi(y_1,y_2) = -\phi(y_2,y_1)$?

You cannot. Consider $$f_1(y_1,y_2) = \frac{1}{2}(y_1 + y_2),\qquad f_2(y_1,y_2) = \frac{1}{2}(y_1 - y_2).$$ Then, let us take $x_2=0$. In general, $\psi(x_1,0)\neq 0$. We have $$\phi(x_1,x_1) = \psi(x_1,0) \neq 0.$$

The crucial point is that, in the definition of $\psi(x_1,x_2)$, $x_1$ and $x_2$ denote positions of two identical fermions, and this is the reason for $\psi$ to be antisymmetric under the $x_1\leftrightarrow x_2$ transformation.

After the coordinate transformation, $y_1$ and $y_2$ do not necessarily correspond to positions of two fermions. In particular, interchanging the positions of the two fermions doesn't mean that $y_1$ becomes $y_2$ and vice versa. Hence, there is no reason for $\phi$ to be antisymmetric under $y_1\leftrightarrow y_2$.

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By your logic you should get $$ f(y,z) = -f(z,y) \tag{1} $$ In any case, the wavefunction under particle interchange is antisymmetric, the individual electrons are identical. Their properties remain the same. We've only interchanged them, not altered them.

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