Or, at the very least, are there any proofs (say Arnold-Liouville theorem or something like that) that are significantly simplifed by the use of exterior differential calculus, Lie groups, etc?
Liouville's theorem (assuming by that you mean the preservation of phase volumes) is one such example actually.
Suppose that $(M,\omega, H)$ is a Hamiltonian system with symplectic form $\omega$, and $\dim M=2n$. Then $$ \Omega=\omega^{\wedge n}\ \text{(n-fold wedge product)} $$ is the Liouville volume form.
Suppose then that $\mathcal D$ is a compact domain of integration in $M$. The volume is $$ \mathrm{vol}\ \mathcal D=\int_\mathcal D\Omega. $$
Now, let's fix some conventions which may be opposite of what everyone is using, since I don't want to check it now (the reasoning's the same nontheless), if $X\in\mathfrak X(M)$ is a vector field, then $\imath_X\omega$ is its dual where the interior product inserts into the first argument. The dual of the symplectic form is $\omega^\ast\in\mho^2(M)$. If $H$ is the Hamiltonian (then following OPs convention), $$ \mathrm dH=-\imath_{X_H}\omega. $$
Let $\phi_t$ denote the flow of the Hamiltonian vector field $X_H$. The change of volume of the region $\mathcal D$ after evolving it for time $t$ is $$\mathrm{vol}\ \mathcal D(t)=\int_{\phi_t(\mathcal D)}\Omega=\int_\mathcal D\phi_t^\ast\Omega. $$
The time-derivative of this at $t=0$ is $$ \frac{\mathrm d}{\mathrm dt}\mathrm{vol}\ \mathcal D(0)=\frac{\mathrm d}{\mathrm dt}\int_\mathcal D\phi^\ast_t\Omega|_{t=0}=\int_\mathcal D\mathscr L_{X_H}\Omega=\int_\mathcal D \mathrm d\imath_{X_H}\Omega. $$
Here we have used the Cartan formula ($\mathscr L_X=\mathrm d\imath_X+\imath_X\mathrm d$) and the interior product in the last term can be expanded as $$ \imath_{X_H}\Omega=\imath_{X_H}\omega\wedge...\wedge\omega+\omega\wedge\imath_{X_H}\omega\wedge...\wedge\omega=n\imath_{X_H}\omega\wedge...\wedge\omega=-n\mathrm dH\wedge...\wedge\omega. $$
All factors in this product are closed, so $\mathrm d\imath_{X_H}\Omega=0$, hence $$ \frac{\mathrm d}{\mathrm dt}\mathrm{vol}\ \mathcal D(0)=0. $$