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Is it possible to have an object 100% pure white without sky blue or sun color tinting the pure whiteness of the photons reflecting/deflecting off an object? Are there any lights that can produce pure white photons (RGB)? And can we see that the color is white or is our eyes going to trick us into thinking the white is a different color? Can scientist produce what can be seen macroscopically as "pure white".

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To answer the question if there is a completely pure white light source, we need to first understand what white light even is and how we see it.

The images are taken from http://jamie-wong.com/post/color/, which is a great article about exactly this topic.

Color Perception

The human eye doesn't just see a particular wavelength of light and knows what color it is. It has a certain twist to it that makes it not very straight-forward to map a color to a wavelength.

When a light beam enters our eye it hits two different kinds of receptors: rods and cones. The rods only respond to the intensity of any visible light, i.e. the brightness, while the cones react only to light of a certain frequency region.

There are different kinds of cones, each of which is sensitive to a certain wavelength region: one sort reacts to blue, one to green and one to yellow/red light. Their response to a wave of a certain wavelength looks as follows (S, M and L correspond to short, medium and long cones):

enter image description here

As you can see, the short cones are not only sensitive to entirely blue light (440nm), but also to some degree to green and violet light. Same goes for all other cones - their responses overlap.

What happens if purely yellow light enters our eye? It is detected by both the medium and long cones and sends an equally strong signal to our brain, which in turn interprets this as yellow. The short cones don't send any signal in this case. The graphs below show two different spectra, but both are recognized by our brain as the same kind of yellow:

enter image description here

Our eyes cannot differentiate between the monochromatic light of e.g. a sodium lamp and a mixture of a red and green light. This principle is exploited in a monitor, where the intensities of the red, blue and green pixels are adjusted to "trick" the eye into thinking a certain color is shown. In reality, only different ratios of these distinct colors arrive at the cones.

White Light

What do we see as "white"? Our brain interprets a source as white if the cones in the eye send an equal response to the brain (more or less, at least). This could be for example a flat spectrum: the intensity of each wavelength is the same. In a perfect eye (in which the sensitivity for each cone is equal) this would be interpreted as white. This is similar to "white noise", a kind of noise that has a uniform frequency distribution.

A single photon has a tradeoff between how sharply its frequency and its length are defined. A short wave packet has a whole bunch of frequencies in it (it has a large bandwidth), while a wave "packet" with exactly one frequency is basically really spread out (like e.g. a laser).

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  • $\begingroup$ It's not the cells who interpret the frequency: the cells simply absorb the light (with some probability proportional to spectral sensitivity). So both rods and L&M&S cones are sensitive only to brightness. It's the brain who interprets these signals as chromatic or achromatic data. $\endgroup$ – Ruslan Jul 24 '19 at 9:57
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There is no universal and objective way to define "pure white".

The reason for this is that colour perception has two important aspects:

  • there is a "base layer" in the physiological response of the human eye and the biochemistry of the retina, but
  • there is also a psycho-perceptual component in terms of how the brain interprets the signals that come from the retina.

Some components of colour vision can be uniquely determined from the physiology of the human eye, but other aspects depend on the context and on the conditions in which the colour is being perceived. This is the basis for most colour-based optical illusions.

To present just one canonical example, in the image below the squares marked A and B are precisely the same shade ─ and yet, our brains interpret A as being 'darker' than B because of the context they're in:

The terms "white" and "pure white" live within this side of colour vision, and as such, they are always context-dependent. To see how this works in detail, look up "white point" (i.e. the specific colour that's marked as "white" in a given image or illumination, and which is used to help encode and understand the rest of the colours present in it).

So, with that in mind:

Are there any lights that can produce pure white photons (RGB)?

Yes: for any given understanding of what "pure white" means, it is possible to produce an illuminated light field which has that colour, using combinations of red, green and blue lights, but there are multiple different, equally valid, understandings of what "pure white" means.

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    $\begingroup$ ... or, as has been said previously, "Your brain is continuously and egregiously lying to you about what your eyeballs have actually detected". $\endgroup$ – Emilio Pisanty Jul 24 '19 at 11:54
  • $\begingroup$ So can a single photon (or collection of identical photons) be white, or is a single photon always monochromatic? $\endgroup$ – PM 2Ring Jul 26 '19 at 1:27
  • $\begingroup$ damn, can i mark two answers as correct? $\endgroup$ – SF12 Study Jul 26 '19 at 5:04
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    $\begingroup$ @PM2Ring It's possible to have coherent polychromatic single-photon wavepackets, but they evolve in time (i.e. you cannot have them in steady state). But the point is moot anyways - while it's just about possible for human eyes to see single photons, that will generally be through scotopic vision (rods instead of cones) which cannot detect colours. For more info see physics.stackexchange.com/a/307021/8563 $\endgroup$ – Emilio Pisanty Jul 26 '19 at 8:25
  • $\begingroup$ @SF12 No, the system only allows a single answer to be marked as accepted. $\endgroup$ – Emilio Pisanty Jul 26 '19 at 8:26
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I would think that a light source which has an emission spectre $f(\omega)$ that looks something like $$ f(\omega)=\begin{cases} \infty & \text{if infrared} < \omega < \text{ultraviolet}\\ 0 & \text{else} \end{cases} $$ could be considered pure white, but then, as others have pointed out, "pure white" has to be defined.

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  • $\begingroup$ Welcome to Physics! Note that we use MathJax to typeset mathematics; you can find a good tutorial here. $\endgroup$ – Emilio Pisanty Jul 24 '19 at 14:58
  • $\begingroup$ Thank you for the warm welcome, I'll be sure to check out the tutorial! $\endgroup$ – DrLeprikon Jul 25 '19 at 14:00
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You observe white if your RGB cones produce the same, strong signal. If the signal is not strong it will be seen as grey or black.

A white photon should have a sufficiently wide intrinsic bandwidth. Perhaps a pulsed optical laser with a very short pulse length fits the bill. If the pulse length is of the order of a single wavelength the band width covers R, G and B.

"The lasing medium in some dye lasers and vibronic solid-state lasers produces optical gain over a wide bandwidth, making a laser possible which can thus generate pulses of light as short as a few femtoseconds." https://en.m.wikipedia.org/wiki/Pulsed_laser

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  • $\begingroup$ I look at car reflections and i see yellow-blue tints from the sky or sun. $\endgroup$ – SF12 Study Jul 24 '19 at 6:06
  • $\begingroup$ To clarify: the sun itself emits white light. But this light needs to cross the atmosphere before it reaches your eye, during which mainly blue light is scattered away. Therefore the sky looks bluer and the sun looks like a white source without the blue parts: yellowish. $\endgroup$ – ahemmetter Jul 24 '19 at 6:10
  • $\begingroup$ so all (basically) white light is pure white? $\endgroup$ – SF12 Study Jul 24 '19 at 6:51
  • $\begingroup$ “White” is a perceptual concept manufactured by your visual cortex.. It’s quite possible you perceive something as “pure white” while I see it as tinted or off-white. I personally see slightly different colors with each eye, one slightly red and one slightly blue. This is normally imperceptible to me except in specific low-illumination situations, but it’s real and consistent. $\endgroup$ – Jim Garrison Jul 24 '19 at 7:02
  • $\begingroup$ @SF12Study That depends on how you define "pure". Anticipating your definition, I again emphasize that light does not need to contain all wavelengths to be seen as white. $\endgroup$ – my2cts Jul 24 '19 at 7:04

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