When solving the Laplace equation on sphere coordinates you get:
$$ u(r,\theta) = \sum_{n=0}^{\infty}\left( A_n\,r^n + \frac{B_n}{r^{n+1}} \right) P_n(\cos\theta) $$
And it is clear that if you have a system with an spheric condensator and you want the potential inside the sphere you want $B_n = 0$ for all $n$ so that the potential is not infinite when $r \to 0$.
What do you do though for $r > R$? I have seen in some documents that people put $A_n = 0$ for all $n$ but my impression is that this is only necessary for $n > 1$ and so you get:
$$ u(r,\theta) = A_0\,P_0(\cos\theta) + \sum_{n=0}^{\infty}\frac{B_n}{r^{n+1}} P_n(\cos\theta) $$
So my questions are either why should $A_0 = 0$? And if that is not the case, how can one find $A_0$ and $B_0$? You can use the ortonormality of the Legendre polynomials to find all the $B_n$ for $n > 0$ but since $A_0$ and $B_0$ share the same Legendre Polynomial, I don't see how to do it.