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I think I'm missing something quite basic here but consider the process:

$$ e^- + e^+ \rightarrow 2\gamma$$

Fermions have opposite parity to antifermions so the parity quantum number before the process is $P=-1 \times (-1)^L$ where $L$ is the relative orbital angular momentum, which should vanish in the zero momentum frame where the collision is head on. So we start with $P=-1$. The photons on the other hand have the same parity as each other so have parity $P=+1$ (after again noting that they must be heading in opposite directions to each other in the ZMF so have $L=0$).

I think my reasoning about the angular momentum must be wrong, but I don't see why. (Additionally, the same argument says that if this is $L:0\rightarrow 0$ then charge congugation $C$ is not a conserved quantity either.)

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    $\begingroup$ Working in the ZMF does not imply L=0. The two momenta (incoming or outgoing) can be equal and opposite but with a transverse offset between them. $\endgroup$ – RogerJBarlow Jun 1 at 15:17
  • $\begingroup$ @RogerJBarlow so am I right that this can't happen if the collision is perfectly head on, but that just doesn't happen in practice (no phase space volume)? $\endgroup$ – jacob1729 Jun 1 at 15:24
  • $\begingroup$ @RogerJBarlow I think you're right, but I can't visualise this for the QM case where I have infinite extended plane waves impinging on each other from opposite directions. I feel like I shouldn't be needing to rely on specific wave packet shapes just to know if something is possible at all. $\endgroup$ – jacob1729 Jun 1 at 15:26
  • $\begingroup$ Thinking of such a collision like two trucks colliding head on is not helpful because of Heisenberg: $\Delta y$ is zero so $\Delta p_y$ is infinite. Two extended plane waves moving in opposing directions and meeting is a much more valid way to think about it. Then you remember that a plane wave can be expressed as a sum of partial waves en.wikipedia.org/wiki/Plane_wave_expansion. and so the plane wave collapses into a particular $L$ component. $\endgroup$ – RogerJBarlow Jun 1 at 16:04
  • $\begingroup$ you are forgetting the polarization of the photons. similar argument to physics.stackexchange.com/questions/483588/… . see link imsc.res.in/~taushif/pdfs/… $\endgroup$ – anna v Jun 1 at 17:34
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The electron-positron collision state in question has the same quantum numbers as positronium, which may exist in two states. The first of these is the short-lived singlet state $^1S_0$, so $L=S=J=0$, hence $P=-$ and $C=(-)^{L+S}=+$, and this is your parapositronium two-photon mode (must have even number of photons, from C), with symmetric parity-odd wavefunction, $$ \propto (|\hat \epsilon _1\rangle |\hat \epsilon _2\rangle - |\hat \epsilon _2\rangle |\hat \epsilon _1\rangle)(e^{ik(\hat {\mathbf k} \cdot ({\mathbf r}_1- {\mathbf r}_2)-2t)}- e^{ik(\hat {\mathbf k} \cdot ({\mathbf r}_2- {\mathbf r}_1)-2t)} ) , $$ for respective photon polarizations $\hat \epsilon_1, \hat\epsilon_2$.

Should remind you of the neutral pion (a pseudoscalar), and decays just like it into an odd-parity couple of photons.

The other, not sought here, long-lived bound state is orthopositronium, triplet and longer lived, $^3S_1$, so $P=-, ~ C=-$. Hence, it must decay to 3γ, unless it were a virtual γ in production through collision of electron-positron.

(So, does this remind you of the ρ or the J/ψ ?)

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  • $\begingroup$ In the $L=0$ state is the parity not $-1$? Because the electron has $P=1$, the positron $P=-1$ (which way around is irrelevant obviously) and so the product has $P=-1$. This differs from the 2-photon decay products. $\endgroup$ – jacob1729 Jun 1 at 21:11
  • $\begingroup$ My question is not directly concerning $e^-e^+$ bound states but free particles that collide and annihilate. Perhaps if I understood the bound states that would answer my question though, although I think the issue might be my understanding of what $L$ means for incoming beams. $\endgroup$ – jacob1729 Jun 1 at 21:13
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    $\begingroup$ The odd-parity 2γ wavefunction is explicitly and simply given here. $\endgroup$ – Cosmas Zachos Jun 1 at 21:58
  • $\begingroup$ Would you mind copying the odd-parity two photon wavefunction into the answer so I can accept it? My confusion was (at least in part) that I was assuming the two photon wavefunction needed to be even and so the process was parity violating. (The other issue was that I was forgetting partial wave expansions as noted in the comments to my OP.) $\endgroup$ – jacob1729 Jun 16 at 20:33
  • $\begingroup$ Done. I have taught neutral pion decay too many times for any sticking points to still stick... $\endgroup$ – Cosmas Zachos Jun 16 at 21:13

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