The answer is:
$ \sin(\omega) = \frac{\sin(lat)}{\sin(i)} $
this expression has has two solutions:
$ \omega = \arcsin \left( \frac{\sin(lat)}{\sin(i)} \right), \ \ \text{and} \ \ \pi - \arcsin \left( \frac{\sin(lat)}{\sin(i)} \right) $
The second solution matches the diagram.
So if the latitude is 60° and the inclination is 82.5°, then the argument of periapsis (ω) is 119.13225456935°.
(The term ''perigee'' applies only to orbits around the Earth; the correct term for Mercury is ''perihermion''. The general term is ''periapsis''.)
Derivation:
The perihelion direction vector is: $ \vec{q} = [1 \ 0 \ 0] \cdot \operatorname{rot}_z(\omega) \cdot \operatorname{rot}_x(i) $.
where rotz is the rotation matrix about the z axis, and rotx is the rotation matrix about the x axis.
Convert the perihelion direction vector to spherical coordinates, set the latitude equal to 60°, then solve for ω.